Copper(II)-catalyzed oxidative N-nitrosation of secondary and tertiary amines with nitromethane under an oxygen atmosphere

被引：30

作者：

Sakai, Norio ^{[1
]}

Sasaki, Minoru ^{[1
]}

Ogiwara, Yohei ^{[1
]}

机构：

[1] Tokyo Univ Sci RIKADAI, Fac Sci & Technol, Dept Pure & Appl Chem, Noda, Chiba 2788510, Japan

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 58期

关键词：

MILD CONDITIONS; NEF REACTION; HETEROGENEOUS CONDITIONS; MOLECULAR-OXYGEN; NITRIC-OXIDE; SULFURIC ACID/NANO2; NITROSAMINES; DIOXYGEN; AMIDES; AGENT;

D O I：

10.1039/c5cc03675e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The combination of a catalytic amount of Cu(OTf)(2) and less than a stoichiometric amount of 1,8-diazabicyclo[5.4.0] undec-7-ene (DBU) under an O-2 atmosphere effectively promoted the N-nitrosation of both secondary aromatic/aliphatic amines and tertiary aromatic amines with nitromethane (CH3NO2) leading to the preparation of N-nitrosamine derivatives.

引用

页码：11638 / 11641

页数：4

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