Wacker oxidation of terminal olefins in a mixture of [bmim][BF4] and water

被引：36

作者：

Ansari, IA ^{[1
]}

Joyasawal, S

Gupta, MK

Yadav, JS

Gree, R

机构：

[1] Indian Inst Chem Technol, Div Organ Chem 1, Hyderabad 500007, Andhra Pradesh, India

[2] Univ Rennes 1, CNRS, UMR 6510, F-35042 Rennes, France

来源：

TETRAHEDRON LETTERS | 2005年 / 46卷 / 44期

关键词：

Wacker oxidation; ionic liquid; PdCl2; CuCl; alkenes;

D O I：

10.1016/j.tetlet.2005.09.013

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple and efficient PdCl2/CuCl catalyzed oxidation of alkenes has been successfully developed using a mixture of water and the ionic liquid [bmim][BF4] as solvent. Starting from various types of terminal olefins, the corresponding ketones have been prepared under mild reaction conditions and obtained in good to excellent yields after a simple extraction with diethyl ether. Furthermore, it was possible to recycle and reuse the ionic liquid and the catalytic system. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：7507 / 7510

页数：4

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