Electrochemically induced Henry reaction of nitromethane and carbonyl compounds

被引：38

作者：

Elinson, Michail N. ^{[1
]}

Ilovaisky, Alexey I. ^{[1
]}

Merkulova, Valentina M. ^{[1
]}

Barba, Fructuoso ^{[2
]}

Batanero, Belen ^{[2
]}

机构：

[1] ND Zelinskii Inst Organ Chem, Leninsky Prospect 47, Moscow 119991, Russia

[2] Univ Alcala De Henares, Dept Organ Chem, Madrid 28871, Spain

来源：

TETRAHEDRON | 2008年 / 64卷 / 25期

关键词：

electrolysis; electrocatalysis; carbonyl compounds; nitromethane; Henry reaction; beta-nitroalcohols;

D O I：

10.1016/j.tet.2008.04.039

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The electrolysis of carbonyl compounds and nitromethane in methanol or in the mixture of methanol and DMF in an undivided cell results in the formation of corresponding beta-nitroalcohols in 60-75% yields. Thus, the simple electrocatalytic system can produce under mild conditions an electrochemically induced Henry reaction. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：5915 / 5919

页数：5

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