H2O2 and HO- Solvation Dynamics: Solute Capabilities and Solute-Solvent Molecular Interactions

被引：9

作者：

Chen, Jiasheng S. ^{[1
,2
]}

Yao, Chuang ^{[2
]}

Liu, Xinjuan J. ^{[3
]}

Zhang, Xi ^{[4
]}

Sun, Chang Q. ^{[5
]}

Huang, Yongli L. ^{[1
]}

机构：

[1] Xiangtan Univ, Sch Mat Sci & Engn, Minist Educ, Key Lab Lowdimens Mat & Applicat Technol, Xiangtan 411105, Peoples R China

[2] Yangtze Normal Univ, Key Lab Extraordinary Bond Engn & Adv Mat Technol, Chongqing 408100, Peoples R China

[3] China Jiliang Univ, Inst Coordinat Bond Engn, Hangzhou 310018, Zhejiang, Peoples R China

[4] Shenzhen Univ, Inst Nanosurface Sci & Engn, Shenzhen 518060, Peoples R China

[5] Nanyang Technol Univ, Sch EEE, NOVITAS, Singapore 639798, Singapore

来源：

CHEMISTRYSELECT | 2017年 / 2卷 / 27期

基金：

中国国家自然科学基金;

关键词：

Hydroxide; Hydrogen peroxide; Compression; Solvation; Solute-solvent interaction; HYDROGEN-PEROXIDE; WATER ICE; NITRIC-OXIDE; TEMPERATURE; CELLS; COMPRESSION; SCATTERING; ANOMALIES; MECHANISM; DENSITY;

D O I：

10.1002/slct.201701334

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We show spectrometrically that H2O2 and HO- solvation resolves the H-O stretching vibration from the mode of the ordinary water centered at similar to 3200 cm(-1) to its below by O:double left right arrow:O compression. An excessive mode due H2O2 solute appears at similar to 3550 cm(-1) and due HO- at similar to 3610 cm(-1), which features the effect of molecular solute bond-order deficiency. The O:double left right arrow:O compression has the same effect to applied pressure that elongates the solvent H-O bond and shortens the O:H nonbond. The H2O2 is less than the HO- capable of raising the surface stress and transforming the fraction of the H-O bonds because of the involvement of solute-solute interactions.

引用

页码：8517 / 8523

页数：7

共 50 条

[1] DYNAMICS OF SOLUTE-SOLVENT INTERACTIONS
DEMAEYER, LCM
PURE AND APPLIED CHEMISTRY, 1986, 58 (08) : 1105 - 1114
[2] Solvation of diclofenac in water from atomistic molecular dynamics simulations - interplay between solute-solute and solute-solvent interactions
Kozlowska, Mariana
Rodziewicz, Pawel
Utesch, Tillmann
Mroginski, Maria Andrea
Kaczmarek-Kedziera, Anna
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2018, 20 (13) : 8629 - 8639
[3] SOLUTE-SOLVENT INTERACTIONS - A SIMPLE PROCEDURE FOR CONSTRUCTING THE SOLVENT CAVITY FOR RETAINING A MOLECULAR SOLUTE
AGUILAR, MA
DELVALLE, FJO
CHEMICAL PHYSICS, 1989, 129 (03) : 439 - 450
[4] ULTRASONIC INVESTIGATION OF SOLUTE-SOLVENT AND SOLUTE-SOLUTE INTERACTIONS IN AQUEOUS-SOLUTIONS OF BASES, NUCLEOSIDES, AND NUCLEOTIDES .2. PH-DEPENDENT SOLUTE-SOLVENT INTERACTIONS
BUCKIN, VA
SARVAZYAN, AP
DUDCHENKO, EI
HEMMES, P
JOURNAL OF PHYSICAL CHEMISTRY, 1980, 84 (07): : 696 - 699
[5] The effects of solute-solvent electrostatic interactions on solvation dynamics in supercritical CO2 -: art. no. 044505
Ladanyi, BM
Nugent, S
JOURNAL OF CHEMICAL PHYSICS, 2006, 124 (04):
[6] Solute-Solvent Interactions in Aqueous Glycylglycine-CuCl2 Solutions: Acoustical and Molecular Dynamics Perspective
Santosh, Mysore Sridhar
Lyubartsev, Alexander
Mirzoev, Alexander
Bhat, Denthaje Krishna
JOURNAL OF SOLUTION CHEMISTRY, 2011, 40 (09) : 1657 - 1671
[7] (H, Li)Br and LiOH Solvation Bonding Dynamics: Molecular Nonbond Interactions and Solute Extraordinary Capabilities
Sun, Chang Q.
Chen, Jiasheng
Gong, Yinyan
Zhang, Xi
Huang, Yongli
JOURNAL OF PHYSICAL CHEMISTRY B, 2018, 122 (03): : 1228 - 1238
[8] Molecular rotation as a tool for exploring specific solute-solvent interactions
Dutt, GB
CHEMPHYSCHEM, 2005, 6 (03) : 413 - 418
[9] Theoretical representation of solvation in biochemical systems: From discrete solute-solvent interactions to bulk solvation
Orozco, M
Lopez, JM
Colomines, C
Alhambra, C
Busquets, MA
Luque, FJ
INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, 1996, 60 (06) : 1179 - 1187
[10] SOLUTE-SOLVENT INTERACTIONS ON THE SURFACE OF SILICA-GEL .2.
SCOTT, RPW
KUCERA, P
JOURNAL OF CHROMATOGRAPHY, 1979, 171 (APR): : 37 - 48

← 1 2 3 4 5 →