Artificial Photosynthesis: From Molecular Catalysts for Light-driven Water Splitting to Photoelectrochemical Cells

被引:253
作者
Andreiadis, Eugen S. [1 ]
Chavarot-Kerlidou, Murielle [1 ]
Fontecave, Marc [1 ,2 ]
Artero, Vincent [1 ]
机构
[1] Univ Grenoble 1, CNRS, CEA, Lab Chim & Biol Met,DSV iRTSV K, Grenoble, France
[2] Coll France, F-75231 Paris, France
关键词
ACTIVE-SITE MODEL; PHOTOINDUCED HYDROGEN EVOLUTION; OXYGEN-EVOLVING COMPLEX; VISIBLE-LIGHT; IRON HYDROGENASE; ELECTRON-TRANSFER; POLYPYRIDINE COMPLEXES; HOMOGENEOUS CATALYSIS; FUNCTIONAL MODELS; ENERGY-CONVERSION;
D O I
10.1111/j.1751-1097.2011.00966.x
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Photosynthesis has been for many years a fascinating source of inspiration for the development of model systems able to achieve efficient light-to-chemical energetic transduction. This field of research, called "artificial photosynthesis," is currently the subject of intense interest, driven by the aim of converting solar energy into the carbon-free fuel hydrogen through the light-driven water splitting. In this review, we highlight the recent achievements on light-driven water oxidation and hydrogen production by molecular catalysts and we shed light on the perspectives in terms of implementation into water splitting technological devices.
引用
收藏
页码:946 / 964
页数:19
相关论文
共 147 条
[1]   Long-range electron and excitation energy transfer in donor-bridge-acceptor systems [J].
Albinsson, Bo ;
Martensson, Jerker .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, 2008, 9 (03) :138-155
[2]   Photoinduced hydrogen evolution using water soluble viologen-linked trisulfonatophenylporphyrins (TPPSCnV) with hydrogenase [J].
Amao, Y ;
Hiraishi, T ;
Okura, I .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1997, 126 (01) :21-26
[3]   Discrete Cyclic Porphyrin Arrays as Artificial Light-Harvesting Antenna [J].
Aratani, Naoki ;
Kim, Dongho ;
Osuka, Atsuhiro .
ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (12) :1922-1934
[4]   Splitting Water with Cobalt [J].
Artero, Vincent ;
Chavarot-Kerlidou, Murielle ;
Fontecave, Marc .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (32) :7238-7266
[5]   Photoinduced hydrogen evolution with cytochrome c3-viologen-ruthenium(II) triad complex and hydrogenase [J].
Asakura, N ;
Hiraishi, T ;
Kamachi, T ;
Okura, I .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2001, 172 (1-2) :1-7
[6]   Photo-induced electron transfer between photosystem 2 via cross-linked redox hydrogels [J].
Badura, Adrian ;
Guschin, Dmitrii ;
Esper, Berndt ;
Kothe, Tim ;
Neugebauer, Sebastian ;
Schuhmann, Wolfgang ;
Roegner, Matthias .
ELECTROANALYSIS, 2008, 20 (10) :1043-1047
[7]   Light-driven water splitting for (bio-)hydrogen production:: photosystern 2 as the central part of a bioelectrochemical device [J].
Badura, Adrian ;
Esper, Berndt ;
Ataka, Kenichi ;
Grunwald, Christian ;
Woell, Christof ;
Kuhlmann, Juergen ;
Heberle, Joachim ;
Roegner, Matthias .
PHOTOCHEMISTRY AND PHOTOBIOLOGY, 2006, 82 (05) :1385-1390
[8]   Cobaloximes as functional models for hydrogenases. 2. proton electroreduction catalyzed by difluoroborylbis(dimethylglyoximato)cobalt(II) complexes in organic media [J].
Baffert, Carole ;
Artero, Vincent ;
Fontecave, Marc .
INORGANIC CHEMISTRY, 2007, 46 (05) :1817-1824
[9]   The structure of the Mn4Ca2+ cluster of photosystem II and its protein environment as revealed by X-ray crystallography [J].
Barber, James ;
Murray, James W. .
PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY B-BIOLOGICAL SCIENCES, 2008, 363 (1494) :1129-1137
[10]   Photosynthetic energy conversion: natural and artificial [J].
Barber, James .
CHEMICAL SOCIETY REVIEWS, 2009, 38 (01) :185-196