Development of disposable filtering mask recycled materials: Impact of blending with recycled mixed polyolefin and their aging stability

被引:10
作者
Battegazzore, Daniele [1 ]
Cravero, Fulvia [1 ]
Frache, Alberto [1 ]
机构
[1] Politecn Torino, Dipartimento Sci Applicata & Tecnol, Alessandria Site,Viale Teresa Michel 5, I-15121 Alessandria, Italy
关键词
Face mask; Mechanical recycling; Recycled mixed polyolefin; Mechanical properties; Photo degradation; Waste; CARBON-BLACK; POLYPROPYLENE; PLASTICS;
D O I
10.1016/j.resconrec.2021.105974
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
A survey on Covid-19 protecting masks habits carried out on the Italian population at the end of 2020 revealed that disposable face masks are the most used, thus resulting in a considerable quantity of waste. Therefore, a separate collection of these devices based on local platforms such as schools, offices and factories is proposed. This would limit collecting costs, ensure the origin and quantity and simplify the sanitizing treatment of the masks, in order to allow their introduction into the industrial recycling stream of plastic materials. In this scenario, an urban separate waste collection material (namely mixed polyolefin) was selected and melt blended in several ratios with the disposable filtering masks. Two recycling solutions have been envisaged: the use of the filtering part alone or the joint introduction of the ear loops. Compared to the mixed polyolefin, the resulting recycled materials from filtering face masks have lower viscosity but comparable toughness and superior stiffness and strength. The presence of ear loops in the recycled improves the rigidity but slightly decrease the viscosity and worsen both the strength and toughness. Furthermore, conceiving an outdoor application, the stability to photo oxidation was investigated through an accelerated aging process. The elaborated degradation rate of the masks material is similar to a commercial polypropylene, while for the mixed polyolefin is greatly reduced. The mixed compounds have intermediate degradation rates.
引用
收藏
页数:9
相关论文
共 34 条
[1]   Ageing and stabilisation of filled polymers: an overview [J].
Allen, NS ;
Edge, M ;
Corrales, T ;
Childs, A ;
Liauw, CM ;
Catalina, F ;
Peinado, C ;
Minihan, A ;
Aldcroft, D .
POLYMER DEGRADATION AND STABILITY, 1998, 61 (02) :183-199
[2]   Polymer Materials for Respiratory Protection: Processing, End Use, and Testing Methods [J].
Armentano, Ilaria ;
Barbanera, Marco ;
Carota, Eleonora ;
Crognale, Silvia ;
Marconi, Marco ;
Rossi, Stefano ;
Rubino, Gianluca ;
Scungio, Mauro ;
Taborri, Juri ;
Calabro, Giuseppe .
ACS APPLIED POLYMER MATERIALS, 2021, 3 (02) :531-548
[3]   Is it Possible to Mechanical Recycle the Materials of the Disposable Filtering Masks? [J].
Battegazzore, Daniele ;
Cravero, Fulvia ;
Frache, Alberto .
POLYMERS, 2020, 12 (11) :1-18
[4]   Plasticizers, antioxidants and reinforcement fillers from hazelnut skin and cocoa by-products: Extraction and use in PLA and PP [J].
Battegazzore, Daniele ;
Bocchini, Sergio ;
Alongi, Jenny ;
Frache, Alberto .
POLYMER DEGRADATION AND STABILITY, 2014, 108 :297-306
[5]   Waste Polypropylene Plastic Recycling toward Climate Change Mitigation and Circular Economy: Energy, Environmental, and Technoeconomic Perspectives [J].
Bora, Raaj R. ;
Wang, Ralph ;
You, Fengqi .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2020, 8 (43) :16350-16363
[6]   Disposable masks: Disinfection and sterilization for reuse, and non-certified manufacturing, in the face of shortages during the COVID-19 pandemic [J].
Carlos Rubio-Romero, Juan ;
del Carmen Pardo-Ferreira, Maria ;
Antonio Torrecilla-Garcia, Juan ;
Calero-Castro, Santiago .
SAFETY SCIENCE, 2020, 129
[7]   Effect of natural antioxidants on the stability of polypropylene films [J].
Cerruti, Pierfrancesco ;
Malinconico, Mario ;
Rychly, Jozef ;
Matisova-Rychla, Lyda ;
Carfagna, Cosimo .
POLYMER DEGRADATION AND STABILITY, 2009, 94 (11) :2095-2100
[8]   About the effects of Covid-19 on solid waste management [J].
Cesaro, Alessandra ;
Pirozzi, Francesco .
TEMA-JOURNAL OF LAND USE MOBILITY AND ENVIRONMENT, 2020, :59-66
[9]   Study of Recycling Potential of FFP2 Face Masks and Characterization of the Plastic Mix-Material Obtained. A Way of Reducing Waste in Times of Covid-19 [J].
Crespo, Cristina ;
Ibarz, Gemma ;
Saenz, Carlos ;
Gonzalez, Pablo ;
Roche, Sandra .
WASTE AND BIOMASS VALORIZATION, 2021, 12 (12) :6423-6432
[10]   Time-resolved rheology as a tool to monitor the progress of polymer degradation in the melt state - Part I: Thermal and thermo-oxidative degradation of polyamide 11 [J].
Filippone, G. ;
Carroccio, S. C. ;
Mendichi, R. ;
Gioiella, L. ;
Dintcheva, N. Tz ;
Gambarotti, C. .
POLYMER, 2015, 72 :134-141