Synthesis of the First Heteroaryl-Substituted Boryl Complexes: Strong Stabilizing Effects of Boron-Aryl π-Conjugation

被引：6

作者：

Braunschweig, Holger ^{[1
]}

Dewhurst, Rian D. ^{[1
]}

Kramer, Thomas ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

INORGANIC CHEMISTRY | 2015年 / 54卷 / 07期

基金：

欧洲研究理事会;

关键词：

TRIVALENT BORON; SINGLE-PHOTON; FLUORIDE; ACCEPTOR; DONOR; SYSTEMS; ACTIVATION; REDUCTION; HALIDES; BONDS;

D O I：

10.1021/acs.inorgchem.5b00192

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first examples of heteroarylboryl complexes were prepared and have been found to be unreactive toward a range of strong reductants, strong Lewis bases, and halide-abstraction reagents. The inertness of the complexes is attributed to strong p-conjugation between the p-basic heteroaryl groups and the p-acidic boron atom. This hypothesis is supported by comparison of the structural and spectroscopic properties of the heteroarylboryl complexes with analogous previously reported homoarylboryl complexes, with the former showing greater coplanarity of the aryl ring with the boron atom and much less facile reactivity.

引用

页码：3619 / 3623

页数：5

共 47 条

[1] Cationic terminal borylene complexes: Structure/bonding analysis and [4+1] cycloaddition reactivity of a BN vinylidene analogue [J].

Aldridge, Simon ;

Jones, Cameron ;

Gans-Eichler, Timo ;

Stasch, Andreas ;

Kays , Deborah L. ;

Coombs, Natalie D. ;

Willock, David J. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (37) :6118-6122

[2]

[Anonymous], 2009, PERS VIS RAYTR

[3] Synthesis of some halogenated tetraarylborates [J].

Anulewicz-Ostrowska, R ;

Klis, T ;

Krajewski, D ;

Lewandowski, B ;

Serwatowski, J .

TETRAHEDRON LETTERS, 2003, 44 (39) :7329-7331

[4] Synthesis, Structure, and Antifungal Activity of Dihydropyridones Containing Boronate Esters [J].

Appoh, Francis E. ;

Wheaton, Susan L. ;

Vogels, Christopher M. ;

Baerlocher, Felix J. ;

Decken, Andreas ;

Westcott, Stephen A. .

HETEROATOM CHEMISTRY, 2009, 20 (01) :56-63

[5] Base-Stabilized Boryl and Cationic Haloborylene Complexes of Iron [J].

Bissinger, Philipp ;

Braunschweig, Holger ;

Damme, Alexander ;

Dewhurst, Rian D. ;

Kraft, Katharina ;

Kramer, Thomas ;

Radacki, Krzysztof .

CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (40) :13402-13407

[6] Syntheses and Structures of Mono- and Dinuclear Cationic Base-Stabilized Platinum Borylene Complexes [J].

Braunschweig, Holger ;

Radacki, Krzysztof ;

Uttinger, Katharina .

ORGANOMETALLICS, 2008, 27 (22) :6005-6012

[7] Direct Hydroboration of B=B Bonds: A Mild Strategy for the Proliferation of B-B Bonds [J].

Braunschweig, Holger ;

Dewhurst, Rian D. ;

Hoerl, Christian ;

Phukan, Ashwini K. ;

Pinzner, Florian ;

Ullrich, Stefan .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (12) :3241-3244

[8] Short Survey of the Chemical Reduction Behavior of the Base-Stabilized Iron Dichloroboryl Complexes [(η5-C5Me5)Fe(CO)2BCl2(LB)] [J].

Braunschweig, Holger ;

Damme, Alexander ;

Dewhurst, Rian D. ;

Kramer, Thomas ;

Krummenacher, Ivo ;

Phukan, Ashwini K. .

ORGANOMETALLICS, 2014, 33 (02) :604-606

[9] Multiple Reduction of 2,5-Bis(borolyl)thiophene: Isolation of a Negative Bipolaron by Comproportionation [J].

Braunschweig, Holger ;

Dyakonov, Vladimir ;

Engels, Bernd ;

Falk, Zarah ;

Hoerl, Christian ;

Klein, Johannes H. ;

Kramer, Thomas ;

Kraus, Hannes ;

Krummenacher, Ivo ;

Lambert, Christoph ;

Walter, Christof .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (49) :12852-12855

[10] A Base-stabilized Iodoborylene Complex of Platinum(II) [J].

Braunschweig, Holger ;

Brenner, Peter B. ;

Dewhurst, Rian D. ;

Radacki, Krzysztof .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2013, 68 (5-6) :747-749

← 1 2 3 4 5 →