Experimental and quantum-chemical investigation of thermolysis of adamantyl-substituted organosilicon peroxides

被引：0

作者：

Nho, BI

Butov, GM

Dumskii, SY

Sabirov, ZM

Urazbaev, VN

Monakov, YB

机构：

[1] Russian Acad Sci, Ufa Res Ctr, Inst Organ Chem, Ufa 450054, Russia

[2] Volgograd State Tech Univ, Volgograd 400066, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 1998年 / 47卷 / 07期

关键词：

adamantane; organosilicon peroxides; thermolysis; MNDO;

D O I：

10.1007/BF02495547

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The kinetics and mechanism of thermal decomposition of adamantyl-containing organosilicon peroxides in a solution in n-nonane were studied. The relationship between the structure of the peroxide and the rate and mechanism of thermalysis was established. The effect of the peroxide structure on the electronic characteristics of the peroxide band was studied by the MNDO method. The heterolytic rearrangement occurring during the decomposition of peroxides was analyzed.

引用

页码：1280 / 1283

页数：4

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