Isobaric vapor-liquid equilibria in the systems 2,2'-oxybis[propane] plus propanol and methyl ethanoate plus 2,2'-oxybis[propane]

被引：1
|
作者：
Wisniak, J
Blacher, D
Grooper, D
机构：
[1] Department of Chemical Engineering, Ben-Gurion University of the Negev, Beer-Sheva
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1996年 / 41卷 / 06期
关键词：
D O I：
10.1021/je960209l
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Vapor-liquid equilibrium at 92 kPa has been determined for the binary systems 2,2'-oxybis[propane] (diisopropyl ether) + propanol and methyl ethanoate + 2,2'-oxybis[propane]. Both systems exhibit moderate positive deviations from ideal behavior; the system methyl ethanoate + 2,2'-oxybis(propane] forms an azeotrope that boils at 360.05 K and contains 79.3 mol % methyl ethanoate. The activity coefficients and boiling point of the solution were correlated with its composition by the Redlich-Kister, Wohl, Wilson, UNIQUAC, NRTL, and Wisniak-Tamir equations.
引用
收藏
页码：1481 / 1484
页数：4
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