Modified Hydrogen Peroxide Bleaching of Bamboo Chemo-mechanical Pulp Using Aqueous Alcohol Media

被引:4
作者
Liang, Fangmin [1 ]
Fang, Guigan [1 ]
Jiao, Jian [1 ]
Deng, Yongjun
Han, Shanming
Li, Hongbin
Tian, Qingwen
Pan, Aixiang
Zhu, Beiping
机构
[1] CAF, Inst Chem Ind Forest Prod, Natl Engn Lab Biomass Chem Utilizat, Key Lab Forest Chem Engn,SFA,Key Lab Biomass Ener, Nanjing 210042, Jiangsu, Peoples R China
关键词
Bamboo; Hydrogen peroxide; Chemo-mechanical pulp; Bleaching; ASPEN CTMP;
D O I
10.15376/biores.14.1.870-881
中图分类号
TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];
学科分类号
0805 ; 080502 ; 0822 ;
摘要
The brightness of bleached bamboo chemo-mechanical pulp (CMP) is often too low to be used as a furnish in value-added paper products. In this study, preliminary optimization of various parameters of a modified hydrogen peroxide (H2O2) bleaching procedure for bamboo CMP pulps was performed using the inclusion of ethanol in the bleaching medium (IEBM). Compared with a conventional bleaching method, this modified process is aimed at improving bleaching efficiency and brightness ceiling of bamboo CMP with the proper usage of chemicals. The CMP was bleached to a brightness of 74.2% ISO at the usage level of 12% H2O2, which shows it increased by 7.4% ISO compared with the conventional method. For a brightness target of 72.0% ISO, bleaching with the IEBM method reduced the H2O2 consumption by approximately 60%. In addition, a higher activation energy of H(2)O(2 )for the IEBM method was calculated to be 23.3 kJ/mol, which was increased by 3.3 kJ/mol compared with the conventional method.
引用
收藏
页码:870 / 881
页数:12
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