Molecules that assemble by sound: An application to the instant gelation of stable organic fluids

被引：331

作者：

Naota, T ^{[1
]}

Koori, H ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn Sci, Dept Chem, PRESTO,Japan Sci & Technol Agcy, Toyonaka, Osaka 5608531, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 26期

关键词：

D O I：

10.1021/ja050809h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first molecule that assembles by ultrasound is described. An association-inert dinuclear Pd complex, anti-1a, which is stabilized by intramolecular π-stacking interactions, gelatinizes a variety of organic solvents instantly upon brief presonication for a few seconds. This is the first quick, positive, and reversible method for the remote switching of stable sol-gel phases. Uniquely, the rate can be precisely controlled over the range between no gelation" and "instant gelation" simply by tuning the sonication time. Copyright © 2005 American Chemical Society."

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页码：9324 / 9325

页数：2

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