共 41 条
[41]
ZHOU MS, 1994, J ORGANOMET CHEM, V476, pC32
Facile reductive excision of sulfur from a {Pt2S2} core in [Pt-2(PPh(3))(4)(mu-S)(2)] to a {Pt2S} triangle by carbon monoxide
被引：0
作者：
Chin, CH
[1
]
Hor, TSA
[1
]
机构：
[1] NATL UNIV SINGAPORE, FAC SCI, DEPT CHEM, SINGAPORE 117548, SINGAPORE
关键词：
platinum;
sulfide;
carbon monoxide;
reductive carbonylation;
carbonyl sulfide;
desulfurization;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ;
081704 ;
摘要：
A synthetic path is established in which [Pt-2(CO)(x)(PPh(3))(4-x)(mu-S)] (x = 0-2) can be prepared from [Pt-2(PPh(3))(4)(mu-S)(2)] under CO at low pressure whereby reductive desulfurization of a {(Pt2S2)-S-II} core gives way to a Pt-Pt bonded ((Pt2S)-S-I) triangle with extrusion of COS gas.
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页码：101 / 104
页数：4
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