First experimental investigation of Th4+ doped barium cerate as electrolytes for intermediate-temperature solid oxide fuel cells

被引:4
作者
Tao, Zetian [1 ,2 ,3 ]
Wang, Yaxing [1 ,2 ]
Wang, Yanlong [1 ,2 ]
Diwu, Juan [1 ,2 ,3 ]
Chai, Zhifang [1 ,2 ,3 ]
Wang, Shuao [1 ,2 ]
机构
[1] Soochow Univ, Sch Radiol & Interdisciplinary Sci RAD X, 199 Renai Rd, Suzhou 215123, Peoples R China
[2] Collaborat Innovat Ctr Radiat Med Jiangsu Higher, 199 Renai Rd, Suzhou 215123, Peoples R China
[3] Yancheng Inst Technol, Key Lab Adv Technol Environm Protect Jiangsu Prov, Yancheng 224001, Jiangsu, Peoples R China
基金
中国博士后科学基金; 中国国家自然科学基金;
关键词
Ceramics; Nuclear materials; Energy storage and conversion; Thin films; BACEO3-BASED PROTON CONDUCTOR;
D O I
10.1016/j.ceramint.2016.07.186
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Barium cerate doped with tetravalent Th is successfully synthesized by a traditional Pechni method. The BaCe0.7Th0.1Y0.2O3-delta (BCT71) composites were applied to an anode supported coin single cell consisting of Ni-BCT71 anode/BCT71 electrolyte/ BCT71-La0.7Sr0.3FeO3-delta cathode. The assembled cell is tested from 600 degrees C to 700 degrees C with humidified hydrogen (similar to 3% H2O) as the fuel and the static air as the oxidant. An open-circuit potential of 0.93 V and a maximum power density of 104 mW cm(-2) are obtained for the single cell with an interface resistance of 0.98 Omega cm(2) at 700 degrees C. (C) 2016 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
引用
收藏
页码:17897 / 17900
页数:4
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