Synthesis and characterization of dicationic nickel complexes

被引：12

作者：

DeSouza, RF ^{[1
]}

Monteriro, AL ^{[1
]}

Seferin, M ^{[1
]}

DeSouza, MO ^{[1
]}

Stedile, FC ^{[1
]}

Wyrvalski, CN ^{[1
]}

Baumvol, IJR ^{[1
]}

机构：

[1] UNIV FED RIO GRANDE SUL,INST FIS,BR-91540000 PORTO ALEGRE,RS,BRAZIL

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1996年 / 40卷 / 04期

关键词：

nickel complexes; dicationic complexes; synthesis; characterization;

D O I：

10.1080/00958979608024535

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dicationic nickel complexes have been prepared by chemical and electrochemical oxidation of metallic nickel, by methathetical exchange of nickel chloride with halide abstracting agents (ZnCl2, Zn, AlCl3, Al) and by reaction of nickel acetate with strong Bronsted acids (HBF4, CF3SO3H). The resulting complexes were characterized by IR, UV-vis, Rutherford Backscattering Spectroscopy (RBS), and magnetic moment measurements as being octahedral, with six nitrile ligands.

引用

页码：311 / 318

页数：8

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