Co-pyrolysis characteristics and kinetic analysis of organic food waste and plastic

被引:144
作者
Tang, Yijing [1 ]
Huang, Qunxing [1 ]
Sun, Kai [1 ]
Chi, Yong [1 ]
Yan, Jianhua [1 ]
机构
[1] Zhejiang Univ, State Key Lab Clean Energy Utilizat, Hangzhou 310027, Zhejiang, Peoples R China
基金
中国国家自然科学基金;
关键词
Co-pyrolysis; Thermogravimetric analysis; Kinetic; Tar; NITROGEN TRANSFORMATION; PVC; BIOMASS; MICROALGAE; GASIFICATION; FERMENTATION; CELLULOSE; BEHAVIOR; FURNACE; MODEL;
D O I
10.1016/j.biortech.2017.09.210
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
In this work, typical organic food waste (soybean protein (SP)) and typical chlorine enriched plastic waste (polyvinyl chloride (PVC)) were chosen as principal MSW components and their interaction during co-pyrolysis was investigated. Results indicate that the interaction accelerated the reaction during co-pyrolysis. The activation energies needed were 2-13% lower for the decomposition of mixture compared with linear calculation while the maximum reaction rates were 12-16% higher than calculation. In the fixed-bed experiments, interaction was observed to reduce the yield of tar by 2-69% and promote the yield of char by 13-39% compared with linear calculation. In addition, 2-6 times more heavy components and 61-93% less nitrogen-containing components were formed for tar derived from mixtures.
引用
收藏
页码:16 / 23
页数:8
相关论文
共 42 条
[1]   Microwave treatment of electric arc furnace dust with PVC: Dielectric characterization and pyrolysis-leaching [J].
Al-harahsheh, Mohammad ;
Kingman, Sam ;
Al-Makhadmah, Leema ;
Hamilton, Ian E. .
JOURNAL OF HAZARDOUS MATERIALS, 2014, 274 :87-97
[2]   A pyrolysis study for the thermal and kinetic characteristics of an agricultural waste with two different plastic wastes [J].
Cepeliogullar, Ozge ;
Putun, Ayse E. .
WASTE MANAGEMENT & RESEARCH, 2014, 32 (10) :971-979
[3]   Thermal and kinetic behaviors of biomass and plastic wastes in co-pyrolysis [J].
Cepeliogullar, Ozge ;
Putun, Ayse E. .
ENERGY CONVERSION AND MANAGEMENT, 2013, 75 :263-270
[4]   Production of low-tar producer gas from air gasification of mixed plastic waste in a two-stage gasifier using olivine combined with activated carbon [J].
Cho, Min-Hwan ;
Mun, Tae-Young ;
Kim, Joo-Sik .
ENERGY, 2013, 58 :688-694
[5]  
Esckilsen B., 2008, Plast. Addit. Compd, V10, P28, DOI [10.1016/S1464-391X(08)70226-5, DOI 10.1016/S1464-391X(08)70226-5]
[6]   Pyrolysis process for the treatment of food waste [J].
Grycova, Barbora ;
Koutnik, Ivan ;
Pryszcz, Adrian .
BIORESOURCE TECHNOLOGY, 2016, 218 :1203-1207
[7]   Formation of HNCO, HCN, and NH3 from the pyrolysis of bark and nitrogen-containing model compounds [J].
Hansson, KM ;
Samuelsson, J ;
Tullin, C ;
Åmand, LE .
COMBUSTION AND FLAME, 2004, 137 (03) :265-277
[8]   Syngas production from pyrolysis of municipal solid waste (MSW) with dolomite as downstream catalysts [J].
He, Maoyun ;
Xiao, Bo ;
Liu, Shiming ;
Hu, Zhiquan ;
Guo, Xianjun ;
Luo, Siyi ;
Yang, Fan .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2010, 87 (02) :181-187
[9]   Investigation on thermochemical behaviour of low rank Malaysian coal, oil palm biomass and their blends during pyrolysis via thermogravimetric analysis (TGA) [J].
Idris, Siti Shawalliah ;
Rahman, Norazah Abd ;
Ismail, Khudzir ;
Alias, Azil Bahari ;
Rashid, Zulkifli Abd ;
Aris, Mohd Jindra .
BIORESOURCE TECHNOLOGY, 2010, 101 (12) :4584-4592
[10]   Recycling of food waste as nutrients in Chlorella vulgaris cultivation [J].
Lau, Kin Yan ;
Pleissner, Daniel ;
Lin, Carol Sze Ki .
BIORESOURCE TECHNOLOGY, 2014, 170 :144-151