Alginate-based aerogels with double catalytic activity sites and high mechanical strength

被引:37
作者
Hou, Yaheng [1 ,2 ]
Zhong, Xin [1 ,2 ]
Ding, Yangyang [1 ,2 ]
Zhang, Shenghu [1 ,2 ]
Shi, Fengwei [1 ,2 ]
Hu, Jianglei [1 ,2 ]
机构
[1] Changchun Univ Technol, Adv Inst Mat Sci, Changchun 130012, Peoples R China
[2] Changchun Univ Technol, Sch Chem Engn, Changchun 130012, Peoples R China
关键词
Alginate; Double catalytic activity sites; Graphene oxide; Mechanical strength; Aerogels; SILICA-AEROGEL; ANISOTROPIC AEROGELS; GRAPHENE; PERFORMANCE; MEMBRANE; HYDROGEL; SURFACE;
D O I
10.1016/j.carbpol.2020.116490
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Aerogel nanocomposites from biomass are one of the attractive emerging materials in the field of material chemistry and catalyst industry, but their lower catalytic efficiency and mechanical performance have limited their wide range applications. In this work, alginate-based aerogels with perfect catalytic performance and great mechanical strength were prepared through incorporating graphene oxide (GO) and SiO2 via a simple one-pot reaction. GO played as the second catalytic activity sites and endowed the aerogels the perfect catalytic per-formance (conversion of phenol reached 90.1 % in phenol hydroxylation reaction). Meanwhile, SiO2 and GO could improve the particle compressive strength of the aerogel to 36.0 kg/cm(2). This alginate-based aerogel provides a novel and environmentally friendly catalyst for next generation catalytic industry.
引用
收藏
页数:7
相关论文
共 46 条
[1]   Polymer composite hydrogels containing carbon nanomaterials-Morphology and mechanical and functional performance [J].
Alam, Ashraful ;
Zhang, Yongjun ;
Kuan, Hsu-Chiang ;
Lee, Sang-Heon ;
Ma, Jun .
PROGRESS IN POLYMER SCIENCE, 2018, 77 :1-18
[2]   Ice-Assisted Assembly of Liquid Crystalline Cellulose Nanocrystals for Preparing Anisotropic Aerogels with Ordered Structures [J].
Chu, Guang ;
Qu, Dan ;
Zussman, Eyal ;
Xu, Yan .
CHEMISTRY OF MATERIALS, 2017, 29 (09) :3980-3988
[3]   Review of Hydrogels and Aerogels Containing Nanocellulose [J].
De France, Kevin J. ;
Hoare, Todd ;
Cranston, Emily D. .
CHEMISTRY OF MATERIALS, 2017, 29 (11) :4609-4631
[4]   Optimization of dye adsorption capacity and mechanical strength of chitosan aerogels through crosslinking strategy and graphene oxide addition [J].
de Luna, M. Salzano ;
Ascione, C. ;
Santillo, C. ;
Verdolotti, L. ;
Lavorgna, M. ;
Buonocore, G. G. ;
Castaldo, R. ;
Filippone, G. ;
Xia, H. ;
Ambrosio, L. .
CARBOHYDRATE POLYMERS, 2019, 211 :195-203
[5]   Silica aerogel; synthesis, properties and characterization [J].
Dorcheh, A. Soleimani ;
Abbasi, M. H. .
JOURNAL OF MATERIALS PROCESSING TECHNOLOGY, 2008, 199 (1-3) :10-26
[6]   The chemistry of graphene oxide [J].
Dreyer, Daniel R. ;
Park, Sungjin ;
Bielawski, Christopher W. ;
Ruoff, Rodney S. .
CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) :228-240
[7]   Remarkable supercapacitor performance of petal-like LDHs vertically grown on graphene/polypyrrole nanoflakes [J].
Du, Dongfeng ;
Wu, Xiaozhong ;
Li, Shuo ;
Zhang, Yu ;
Xing, Wei ;
Li, Li ;
Xue, Qingzhong ;
Bai, Peng ;
Yan, Zifeng .
JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (19) :8964-8971
[8]   Graphenes as Efficient Metal-Free Fenton Catalysts [J].
Espinosa, Juan C. ;
Navalon, Sergio ;
Primo, Ana ;
Moral, Monica ;
Fernandez Sanz, Javier ;
Alvaro, Mercedes ;
Garcia, Hermenegildo .
CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (34) :11966-11971
[9]   Mechanically strong graphene oxide/sodium alginate/polyacrylamide nanocomposite hydrogel with improved dye adsorption capacity [J].
Fan, Jinchen ;
Shi, Zixing ;
Lian, Min ;
Li, Hong ;
Yin, Jie .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (25) :7433-7443
[10]   Electronic Structure Tuning in Ni3FeN/r-GO Aerogel toward Bifunctional Electrocatalyst for Overall Water Splitting [J].
Gu, Yu ;
Chen, Shuai ;
Ren, Jun ;
Jia, Yi Alec ;
Chen, Chengmeng ;
Komarneni, Sridhar ;
Yang, Dongjiang ;
Yao, Xiangdong .
ACS NANO, 2018, 12 (01) :245-253