Two Metal-Organic Frameworks Based on Tricarboxylic Acid: Syntheses, Structures and Fluorescent Properties

被引：0

作者：

Zhao Can ^{[1
]}

Zhang You ^{[1
]}

Xie Meng-Lin ^{[1
]}

Wu Meng-Qin ^{[1
]}

Wen Yi-Hang ^{[1
]}

机构：

[1] Zhejiang Normal Univ, Inst Phys Chem, Zhejiang Key Lab React Chem Solid Surfaces, Jinhua 321004, Zhejiang, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2015年 / 31卷 / 04期

关键词：

metal-organic frameworks; 1,3-bis(4 '-carboxylphenoxy)benzoic acid; hydrothermal reaction; topology; luminescent property; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; TRIPODAL LIGAND; LUMINESCENCE; COMPLEXES; SERIES; ADSORPTION; PHOTOLUMINESCENCE; ABSORPTION; DIVERSITY;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two metal-organic frameworks (MOFs), formulated as [Cd-2(CH3COO)(L)(H2O)(2)](n) (1) and [Na(H2L)](n) (2) (H3L=1,3-bis(4'-carboxylphenoxy)benzoic acid) were successfully prepared by hydrothermal reaction of H3L ligand with metal salts. Because of the various coordination modes of the H3L ligand, these compounds display structural diversity. Compound 1 crystallizes in triclinic system with P (1) over bar space group and 2 in monoclinic system with C2/c space group. The single crystal structures show that 1 possesses a 3D structural framework, in which the secondary building units(SBUs) are bridged by the L3- ligands, 2 features a 3D 5-connected network with (4(6)center dot 6(4)) topology. Moreover, the luminescent property of compound 1 has been investigated. CCDC: 1009539, 1; 1009540, 2.

引用

页码：781 / 788

页数：8

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