Second generation N-heterocyclic carbene-Pt(0) complexes as efficient catalysts for the hydrosilylation of alkenes

被引：90
作者：
Buisine, O
Berthon-Gelloz, G
Brière, JF
Stérin, S
Mignani, G
Branlard, P
Tinant, B
Declercq, JP
Markó, IE
机构：
[1] Catholic Univ Louvain, Dept Chim, Unite Chim Organ & Med, B-1348 Louvain, Belgium
[2] Catholic Univ Louvain, Unite Anal Struct, B-1348 Louvain, Belgium
[3] Rhodia Ctr Rech Lyon, F-69192 St Fons, France
[4] ENSICAEN, CNRS, Lab Chim Mol & Thioorgan, UMR 6507, F-14050 Caen, France
来源：
CHEMICAL COMMUNICATIONS | 2005年 / 30期
关键词：
D O I：
10.1039/b506369h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new class of benzimidazolylidene carbene-Pt(0) complexes was developed and used to efficiently catalyse the hydrosilylation of alkenes.
引用
收藏
页码：3856 / 3858
页数：3
相关论文
共 28 条
[1]   STEREOCHEMICAL NONRIGIDITY IN A CHELATED PLATINUM(0)-DIOLEFIN COMPLEX [J].
BASSINDALE, AR ;
BROWN, SSD ;
LO, P .
ORGANOMETALLICS, 1994, 13 (02) :738-740
[2]   Imidazoline-2-ylidene metal complexes with pendant ferrocenyl substituents [J].
Bildstein, B ;
Malaun, M ;
Kopacka, H ;
Ongania, KH ;
Wurst, K .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 552 (1-2) :45-61
[3]   A CONVENIENT AND NOVEL ROUTE TO BIS(ETA-ALKYNE)PLATINUM(0) AND OTHER PLATINUM(0) COMPLEXES FROM SPEIER HYDROSILYLATION CATALYST H2[PTCL6].XH2O - X-RAY STRUCTURE OF [PT((ETA-CH2=CHSIME2)2O)(P-TERT-BU3)] [J].
CHANDRA, G ;
LO, PY ;
HITCHCOCK, PB ;
LAPPERT, MF .
ORGANOMETALLICS, 1987, 6 (01) :191-192
[4]   SYNTHESIS OF TRANS-DI-MU-HYDRIDO-BIS(SILYL)BIS(TRIALKYLPHOSPHINE)DIPLATINUM COMPLEXES - CRYSTAL AND MOLECULAR-STRUCTURE OF DI-MU-HYDRIDOBIS(TRICYCLOHEXYLPHOSPHINE)BIS(TRIETHYLSILYL)DIPLATINUM [J].
CIRIANO, M ;
GREEN, M ;
HOWARD, JAK ;
PROUD, J ;
SPENCER, JL ;
STONE, FGA ;
TSIPIS, CA .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1978, (07) :801-808
[5]   HYDROSILYLATION OF OLEFINS CATALYZED BY TRANS-DI-MU-HYDRIDO-BIS(TRICYCLO-HEXYLPHOSPHINE)BIS(SILYL)DIPLATINUM COMPLEXES [J].
GREEN, M ;
SPENCER, JL ;
STONE, FGA ;
TSIPIS, CA .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (16) :1519-1525
[6]  
Hahn FE, 1999, CHEM-EUR J, V5, P1931, DOI 10.1002/(SICI)1521-3765(19990604)5:6<1931::AID-CHEM1931>3.3.CO
[7]  
2-D
[8]   Iridium complexes with N-allyl-substituted benzimidazol-2-ylidene ligands and their application in catalytic transfer hydrogenation [J].
Hahn, FE ;
Holtgrewe, C ;
Pape, T ;
Martin, M ;
Sola, E ;
Oro, LA .
ORGANOMETALLICS, 2005, 24 (09) :2203-2209
[9]   Synthesis of benzannulated N-heterocyclic carbene ligands by a template synthesis from 2-nitrophenyl isocyanide [J].
Hahn, FE ;
Plumed, CG ;
Münder, M ;
Lügger, T .
CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (24) :6285-6293
[10]  
HAHN FE, 1999, J ORGANOMET CHEM, P585
123