Dual functionalities of hydrogen-bonding self-assembled catalysts in chelation-assisted hydroacylation

被引：20
作者：
Park, Jung-Woo [1 ]
Park, Ji-Hye [1 ]
Jun, Chul-Ho [1 ]
机构：
[1] Yonsei Univ, Dept Chem, CBMH, Seoul 120749, South Korea
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2008年 / 73卷 / 14期
关键词：
D O I：
10.1021/jo800862q
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A recyclable catalyst for chelation-assisted hydroacylation of an olefin with primary alcohol was developed using hydrogen-bonding self-assembled catalysts consisting of 2,6-diaminopyridine and barbiturate phosphine-rhodium(I) complex. Upon heating, these two catalysts act as homogeneous catalysts due to cleavage of the hydrogen bond, and these associate to form supramolecular assemblies via hydrogen bonding that can be separated from immiscible product phase upon cooling after the reaction.
引用
收藏
页码：5598 / 5601
页数：4
相关论文
共 50 条
  • [21] Room temperature bonding of Au assisted by self-assembled monolayer
    Takeuchi, Kai
    Wang, Junsha
    Kim, Beomjoon
    Suga, Tadatomo
    Higurashi, Eiji
    APPLIED PHYSICS LETTERS, 2023, 122 (05)
  • [22] Hydrogen-Bonding versus van der Waals Interactions in Self-Assembled Mono layers of Substituted Isophthalic Acids
    Dickerson, Pearl N.
    Hibberd, Amber M.
    Oncel, Nuri
    Bernasek, Steven L.
    LANGMUIR, 2010, 26 (23) : 18155 - 18161
  • [23] Chelation-assisted carbon-hydrogen and carbon-carbon bond activation by transition metal catalysts
    Jun, CH
    Moon, CW
    Lee, DY
    CHEMISTRY-A EUROPEAN JOURNAL, 2002, 8 (11) : 2423 - 2428
  • [24] Crystallization manipulation of poly(butylene succinate) via hydrazide-based self-assembled hydrogen-bonding interactions
    Yang, Lu-Lu
    Wei, Xue-Wei
    Wu, Tianyu
    Ye, Hai-Mu
    POLYMER, 2024, 298
  • [25] Hydrogen-bonding, self-assembled monolayers: Ordered molecular films for study of through-peptide electron transfer
    Clegg, RS
    Hutchison, JE
    LANGMUIR, 1996, 12 (22) : 5239 - 5243
  • [26] SELF-ASSEMBLED MOLECULAR CAPSULE BASED ON THE HYDROGEN-BONDING INTERACTION BETWEEN 2 DIFFERENT CALIX[4]ARENES
    KOH, K
    ARAKI, K
    SHINKAI, S
    TETRAHEDRON LETTERS, 1994, 35 (44) : 8255 - 8258
  • [27] Hydrogen-Bonding Strength Influences Hierarchical Self-Assembled Structures in Unusual Miscible/Immiscible Diblock Copolymer Blends
    Tseng, Tzu-Chun
    Kuo, Shiao-Wei
    MACROMOLECULES, 2018, 51 (16) : 6451 - 6459
  • [28] Syntheses and energy transfer in multiporphyrinic arrays self-assembled with hydrogen-bonding recognition groups and comparison with covalent steroidal models
    Balaban, Teodor Silviu
    Berova, Nina
    Drain, Charles Michael
    Hauschild, Robert
    Huang, Xuefei
    Kalt, Heinz
    Lebedkin, Serri
    Lehn, Jean-Marie
    Nifaitis, Fotis
    Pescitelli, Gennaro
    Prokhorenko, Valentyn I.
    Riedel, Gernot
    Smeureanu, Gabriela
    Zeller, Joachim
    CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (30) : 8411 - 8427
  • [29] Temperature-Triggered Self-Assembled Structural Transformation: From Pure Hydrogen-Bonding Quadrilateral Nanonetwork to Trihexagonal Structures
    Zhang, Si-Qi
    Cheng, Lin-Xiu
    Gong, Zhong-Liang
    Duan, Wu-Biao
    Tu, Bin
    Zhong, Yu-Wu
    Zeng, Qing-Dao
    LANGMUIR, 2019, 35 (20) : 6571 - 6577
  • [30] Self-assembled discotic liquid crystals formed by hydrogen bonding of alkoxystilbazoles
    Lee, JH
    Han, MJ
    Hwang, SH
    Jang, I
    Lee, SJ
    Yoo, SH
    Jho, JY
    Park, SY
    TETRAHEDRON LETTERS, 2005, 46 (42) : 7143 - 7146
12345