Syntheses and structures of Ar3Sb5 and Ar4Sb4 compounds (Ar = C6H3-2,6-(CH2NMe2)2)

被引：41

作者：

Dostal, Libor ^{[1
]}

Jambor, Roman ^{[1
]}

Ruzicka, Ales ^{[1
]}

Holecek, Jaroslav ^{[1
]}

机构：

[1] Univ Pardubice, Fac Chem Technol, Dept Gen & Inorgan Chem, Pardubice 53210, Czech Republic

来源：

ORGANOMETALLICS | 2008年 / 27卷 / 10期

关键词：

D O I：

10.1021/om800227m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Sb5Ar3 (Ar = N,C,N chelating ligand, C6H3-2,6(CH2NMe2)(2))) trigonal bipyramidal cluster was obtained as one of two products (along with a tetrameric Sb4Ar4 compound) by reduction of the parent ArSbCl2 compound.

引用

页码：2169 / 2171

页数：3

共 32 条

[1] STABLE HOMOPOLYATOMIC ANIONS OF POST-TRANSITION METALS - ZINTL IONS - SYNTHESIS AND STRUCTURE OF A SALT CONTAINING HEPTANTIMONIDE(3-) ANION [J].

ADOLPHSON, DG ;

CORBETT, JD ;

MERRYMAN, DJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (23) :7234-7239

[2] EARLY FINDING OF PREFERRED ORIENTATION - A NEW METHOD [J].

ALTOMARE, A ;

CASCARANO, G ;

GIACOVAZZO, C ;

GUAGLIARDI, A .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 :1045-1050

[3] USE OF THE 2,6-BIS[(DIMETHYLAMINO)METHYL]PHENYL LIGAND TO FORM SOME PENTACOORDINATE DERIVATIVES OF P(III), AS(III), SB(III) AND BI(III) [J].

ATWOOD, DA ;

COWLEY, AH ;

RUIZ, J .

INORGANICA CHIMICA ACTA, 1992, 198 :271-274

[4] Synthesis, chemistry, and structures of neopentyl and (trimethylsilyl)methyl antimony and bismuth oligomers [J].

Balázs, G ;

Balázs, L ;

Breunig, HJ ;

Lork, E .

ORGANOMETALLICS, 2003, 22 (14) :2919-2924

[5] Neutron diffraction crystallography of meso-R(H)Sb-Sb(H)R and reactions of R(H)Sb-Sb(H)R and RSbH2 (R = (Me3Si)2CH) leading to tungsten carbonyl complexes, methylstibanes, and antimony homocycles [J].

Balázs, G ;

Breunig, HJ ;

Lork, E ;

Mason, S .

ORGANOMETALLICS, 2003, 22 (03) :576-585

[6] Organometallic compounds with Sb-Sb or Bi-Bi bonds [J].

Balázs, L ;

Breunig, HJ .

COORDINATION CHEMISTRY REVIEWS, 2004, 248 (7-8) :603-621

[7] Outlier treatment in data merging [J].

Blessing, RH .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1997, 30 :421-426

[8] [NA(2,2,2-CRYPT)]3[SB11], A SALT CONTAINING THE UNDECAANTIMONIDE(3-) ANION [J].

BOLLE, U ;

TREMEL, W .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (02) :91-93

[9] Sb8R4, R = (Me3Si)(2)CH - A polycyclic organostibane [J].

Breunig, HJ ;

Rosler, R ;

Lork, E .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (20) :2237-2238

[10] New developments in the chemistry of organoantimony and -bismuth rings [J].

Breunig, HJ ;

Rösler, R .

CHEMICAL SOCIETY REVIEWS, 2000, 29 (06) :403-410

← 1 2 3 4 →