Magnetism of the praseodymium halide thiosilicates Pr3X[SiS4]2 (X = Cl, Br, I)

被引:6
|
作者
Hatscher, ST [1 ]
Urland, W [1 ]
机构
[1] Univ Hannover, Inst Anorgan Chem, D-30167 Hannover, Germany
关键词
magnetism ligand field; angular overlap model; thiosilicates; lanthanide compounds;
D O I
10.1016/S0022-4596(03)00176-2
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The magnetism of the three compounds Pr3X[SiS4](2) (X = Cl, Br, I) has been measured in the temperature range between 1.7 and 300 K. For the theoretical calculations to interpret the magnetic behavior the angular overlap model was employed to reproduce the ligand field influence and the molecular field approach to take magnetic interaction into account. (C) 2003 Elsevier Science (USA). All rights reserved.
引用
收藏
页码:288 / 293
页数:6
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