Adsorption of 2,4-Dichlorophenoxyacetic Acid from Aqueous Solution Using Carbonized Chest Nut as Low Cost Adsorbent: Kinetic and Thermodynamic

被引:18
作者
Gulen, Jale [1 ]
Aslan, Sabri [1 ]
机构
[1] Yildiz Tech Univ, Chem Engn Dept, TR-34210 Istanbul, Turkey
来源
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS | 2020年 / 234卷 / 03期
关键词
active carbon; adsorption; isotherms; kinetic; thermodynamic; ACTIVATED CARBON; REMOVAL; ISOTHERM; 2,4-D; SORPTION; WATER; EQUILIBRIUM; EXTRACTION; HERBICIDES; GASES;
D O I
10.1515/zpch-2019-0004
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The activated carbon was made of carbonized chest nut shell (CCS) and used as low cost adsorbent for 2,4-D (2,4-dichlorophenoxyacetic acid) removal. The experiments were conducted at different temperatures such as 35, 45 and 55 degrees C and this system represents as L type adsorption behavior. The experimental data were modelled using several isotherm models such as Langmuir, Freundlich, Temkin and Dubinin Radushkevich. The adsorption dynamics were searched by applying pseudo first, pseudo second and intra particle diffusion models. The thermodynamic approach was conducted for determining the thermodynamic values of Delta H degrees, Delta S degrees and Delta G degrees.
引用
收藏
页码:461 / 484
页数:24
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