Emission properties of Ce3+ centers in barium borate glasses prepared from different precursor materials

被引：19

作者：

Torimoto, Aya ^{[1
]}

Masai, Hirokazu ^{[1
,4
]}

Okada, Go ^{[2
]}

Kawaguchi, Noriaki ^{[2
]}

Yanagida, Takayuki ^{[2
]}

Ohkubo, Takahiro ^{[3
]}

机构：

[1] Kyoto Univ, Inst Chem Res, Uji, Kyoto 6110011, Japan

[2] Nara Inst Sci & Technol, Grad Sch Mat Sci, 8916-5 Takayama, Nara 6300192, Japan

[3] Chiba Univ, Inage Ku, 1-33 Yayoi Cho, Chiba 2638522, Japan

[4] Natl Inst Adv Ind Sci & Technol, Dept Mat & Chem, 1-8-31 Midorigaoka, Ikeda, Osaka 5630026, Japan

来源：

OPTICAL MATERIALS | 2017年 / 72卷

关键词：

Ce3+ emission center; Alkaline earth ion; Borate glass; Emission; OPTICAL-PROPERTIES; CERIUM FLUORIDE; SILICA; B-11; NMR; CRYSTAL; FIBERS; MAS;

D O I：

10.1016/j.optmat.2017.03.062

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The photoluminescence (PL) and X-ray induced luminescence properties of Ce-doped barium borate glasses prepared from different precursor materials have been investigated. Oxidation of Ce3+ takes place during the melting process performed using a pre-vitrified non-doped glass. Residual groups originated from the precursor materials, such as fluorine atoms and OH groups, are found to affect the optical and emission properties of the glasses. Moreover, both the PL and the X-ray induced luminescence properties of the glasses depend on the precursor materials used for their synthesis. Based on a thorough analysis of the emission properties, we conclude that the best synthesis conditions involve melting a batch containing Ce(CH3COO)(3)center dot H2O, BaCO3, and B2O3 in Ar atmosphere. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：52 / 57

页数：6

共 34 条

[1] CERIUM FLUORIDE - A SCINTILLATOR FOR HIGH-RATE APPLICATIONS [J].

ANDERSON, DF .

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT, 1990, 287 (03) :606-612

[2] Energy migration processes in undoped and Ce-doped multicomponent garnet single crystal scintillators [J].

Bartosiewicz, K. ;

Babin, V. ;

Kamada, K. ;

Yoshikawa, A. ;

Nikl, M. .

JOURNAL OF LUMINESCENCE, 2015, 166 :117-122

[3] Optical properties of Ce3+-doped oxide glasses and correlations with optical basicity [J].

Bei, Jiafang ;

Qian, Gujie ;

Liang, Xiaoluan ;

Yuan, Shuanglong ;

Yang, Yunxia ;

Chen, Guorong .

MATERIALS RESEARCH BULLETIN, 2007, 42 (07) :1195-1200

[4] An infrared spectroscopic study of water-related species in silica glasses [J].

Davis, KM ;

Tomozawa, M .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1996, 201 (03) :177-198

[5] Formation and UV absorption of cerium, europium and terbium ions in different valencies in glasses [J].

Ebendorff-Heidepriem, H ;

Ehrt, D .

OPTICAL MATERIALS, 2000, 15 (01) :7-25

[6] Hydroxyl groups in erbium-doped germanotellurite glasses [J].

Feng, X ;

Tanabe, S ;

Hanada, T .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 2001, 281 (1-3) :48-54

[7] Fluorescence and radiation response properties of Ce3+-doped CaO-Al2O3-B2O3 glass [J].

Fujimoto, Yutaka ;

Yanagida, Takayuki ;

Futami, Yoshisuke ;

Masai, Hirokazu .

JAPANESE JOURNAL OF APPLIED PHYSICS, 2014, 53 (05)

[8] Spectroscopic properties of cerium-doped aluminosilicate glasses [J].

Herrmann, Andreas ;

Othman, Hosam A. ;

Assadi, Achraf A. ;

Tiegel, Mirko ;

Kuhn, Stefan ;

Ruessel, Christian .

OPTICAL MATERIALS EXPRESS, 2015, 5 (04) :720-732

[9] Analysis of OH absorption bands in synthetic silica [J].

Humbach, O ;

Fabian, H ;

Grzesik, U ;

Haken, U ;

Heitmann, W .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1996, 203 :19-26

[10] Effect of hydroxyl content on the physical properties of calcium metaphosphate glasses [J].

Karmakar, B ;

Kundu, P ;

Chaudhuri, AK ;

Annapurna, K ;

Kumar, A ;

Dwivedi, RN .

BULLETIN OF MATERIALS SCIENCE, 1999, 22 (02) :115-119

← 1 2 3 4 →