The critical pulling force for self-avoiding walks

被引:21
作者
Beaton, Nicholas R. [1 ]
机构
[1] Univ Saskatchewan, Dept Math & Stat, Saskatoon, SK, Canada
关键词
self-avoiding walks; polymers; phase transition; MACROMOLECULES; DIMENSIONS; SURFACE;
D O I
10.1088/1751-8113/48/16/16FT03
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Self-avoiding walks (SAWs) are a simple and well-known model of long, flexible polymers in a good solvent. Polymers being pulled away from a surface by an external agent can be modelled with SAWs in a half-space, with a Boltzmann weight y = e(f) associated with the pulling force. This model is known to have a critical point at a certain value y(c) of this Boltzmann weight, which is the location of a transition between the so-called free and ballistic phases. The value y(c) = 1 has been conjectured by several authors using numerical estimates. We provide a relatively simple proof of this result, and show that further properties of the free energy of this system can be determined by re-interpreting existing results about the two-point function of SAWs.
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页数:8
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