A robust, flexible adhesive tape-based SERS substrate fabricated by polymer etching and subsequent Au coating on the exposed SiO2 nanosphere monolayer

被引:5
作者
Cao, Junming [1 ,2 ]
Yang, Jiewen [1 ,2 ]
Wang, Qi [1 ,2 ]
Yuan, Xueguang [1 ,2 ]
Liu, Hao [1 ,2 ]
Pang, Zhenqi [1 ,2 ]
Liu, Kai [1 ,2 ]
Cai, Shiwei [1 ,2 ]
Ren, Xiaomin [1 ,2 ]
机构
[1] Beijing Univ Posts & Telecommun, State Key Lab Informat Photon & Opt Commun, Beijing 100876, Peoples R China
[2] Beijing Univ Posts & Telecommun, Sch Elect Engn, Beijing 100876, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
Flexible SERS substrate; Adhesive tape; Plasma etching; SiO(2 )nanosphere monolayer; Au coating; SURFACE; FILM;
D O I
10.1016/j.saa.2022.121626
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
With the rapid development of trace detection, high-performance flexible surface-enhanced Raman scattering (SERS) substrates have enjoyed steady growth of interest. In this paper, a facile method to improve the robustness of the flexible SERS substrate via the synergistic effect of rigid SiO2 nanospheres and flexible tape was demonstrated for the first time. In detail, the spin-coated SiO2 nanosphere monolayer was transferred from the host silicon wafer into the tape by peeling-off process, followed by O-2 plasma etching of tape polymer to expose the nanospheres, and final Au coating to form plentiful SERS "hotspots ". The as-prepared SERS sample shows a detection limit of Rhodamine 6G (R6G) down to 10(-10) M and can afford a 500 times bending-releasing cyclic test. Our research provides a promising strategy to prepare robust SERS substrates which exhibit good potential in practical molecule detection on curved surfaces.
引用
收藏
页数:6
相关论文
共 23 条
[1]   Recent Progress in Surface-Enhanced Raman Scattering for the Detection of Chemical Contaminants in Water [J].
Bodelon, Gustavo ;
Pastoriza-Santos, Isabel .
FRONTIERS IN CHEMISTRY, 2020, 8
[2]   Surface-enhanced Raman scattering [J].
Campion, A ;
Kambhampati, P .
CHEMICAL SOCIETY REVIEWS, 1998, 27 (04) :241-250
[3]  
Ding SY, 2016, NAT REV MATER, V1, DOI [10.1038/natrevmats.2016.71, 10.1038/natrevmats.2016.21]
[4]   Continuous synthesis of monodisperse silica microspheres over 1 μm size [J].
Fei, Shian ;
Zhang, Yaheng ;
Zhang, Jie ;
Tang, Zhiyong ;
Wu, Qing .
JOURNAL OF FLOW CHEMISTRY, 2021, 11 (04) :831-842
[5]   Synthesis and characterization of water based acrylic Pressure sensitive adhesive of surface protection tape [J].
He Min ;
Zhang Qiuyu ;
Guo Jiying .
EMERGING FOCUS ON ADVANCED MATERIALS, PTS 1 AND 2, 2011, 306-307 :1785-1791
[6]   Understanding self-assembled nanosphere patterns [J].
Járai-Szabó, F ;
Astilean, S ;
Néda, Z .
CHEMICAL PHYSICS LETTERS, 2005, 408 (4-6) :241-246
[7]   Recent advances in surface-enhanced Raman scattering-based sensors for the detection of inorganic ions: Sensing mechanism and beyond [J].
Ji, Wei ;
Li, Linfang ;
Zhang, Yue ;
Wang, Xinnan ;
Ozaki, Yukihiro .
JOURNAL OF RAMAN SPECTROSCOPY, 2021, 52 (02) :468-481
[8]   Surface-Enhanced Raman Scattering Detection of Pesticide Residues Using Transparent Adhesive Tapes and Coated Silver Nanorods [J].
Jiang, Jiaolai ;
Zou, Sumeng ;
Ma, Lingwei ;
Wang, Shaofei ;
Liao, Junsheng ;
Zhang, Zhengjun .
ACS APPLIED MATERIALS & INTERFACES, 2018, 10 (10) :9129-9135
[9]   Creating, characterizing, and controlling chemistry with SERS hot spots [J].
Kleinman, Samuel L. ;
Frontiera, Renee R. ;
Henry, Anne-Isabelle ;
Dieringer, Jon A. ;
Van Duyne, Richard P. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (01) :21-36
[10]   A Wearable Surface-Enhanced Raman Scattering Sensor for Label-Free Molecular Detection [J].
Koh, Eun Hye ;
Lee, Won-Chul ;
Choi, Yeong-Jin ;
Moon, Joung-Il ;
Jang, Jinah ;
Park, Sung-Gyu ;
Choo, Jaebum ;
Kim, Dong-Ho ;
Jung, Ho Sang .
ACS APPLIED MATERIALS & INTERFACES, 2021, 13 (02) :3024-3032