Absolute charge transfer and fragmentation cross sections in He2++C60 collisions

被引:2
|
作者
Diaz-Tendero, S. [1 ,2 ,3 ]
Ruiz, L. F. [3 ]
Zarour, B. [4 ]
Hanssen, J. [4 ]
Alcami, M.
Politis, M. F. [5 ]
Hervieux, P-A [6 ]
Martin, F. [3 ]
机构
[1] CNRS, Lab Collis Atom & Mol, UMR 8625, Batiment 351, F-91405 Orsay, France
[2] Univ Paris 11, UMR 8625, Lab Collisions Atomiques Moleculaires, F-91405 Orsay, France
[3] Univ Autonoma Madrid, Departamento Quim, E-28049 Madrid, Spain
[4] Univ Metz, LPMC, F-57078 Metz 03, France
[5] Univ Paris 06, IMPMC, F-75015 Paris, France
[6] Inst Phys Chimie Materiaux Strasbourg, F-67034 Strasbourg, France
关键词
IONIZATION-POTENTIALS; DISSOCIATION-ENERGIES; C-60; MOLECULE; IONS; EXCITATION; CLUSTERS; EXCHANGE; HE2+;
D O I
10.1088/1742-6596/194/1/012047
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
We present a set of theoretical methods to study the different processes taking place in ion-fullerene collisions. In particular, we focus on charge transfer, excitation and fragmentation processes. These methods have been successfully applied to the case of He2+ + C-60 collisions. We have found that single and double charge transfer cross sections are of the same order of magnitude in the velocity range studied (impact energy similar to 0.1 - 10 keV). Fragmentation of C-60(+) into C-58(+)+C-2 is observed only with large excitation energies and/or if one waits long enough (detecting the fragments at large distances from the collision). The agreement between our predictions and the experimental results supports the validity of the methods presented.
引用
收藏
页数:8
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