Catalytic hydrogenation of carbon dioxide to formic acid in aqueous solutions of polyethylene oxide

被引:0
作者
Karakhanov, EA [1 ]
Egazar'yants, SV
Kardashev, SV
Maksimov, AL
Minos'yants, SS
Sedykh, AD
机构
[1] Moscow MV Lomonosov State Univ, Moscow 119899, Russia
[2] OAO Gazprom, Moscow, Russia
关键词
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The catalytic hydrogenation of carbon dioxide to formic acid in aqueous solutions of polyethylene oxide in the presence of various amines was studied. The rhodium complex formed in situ under the reaction conditions from rhodium(III) chloride and triphenylphosphine was used as the catalyst. The dependence of the yield of formic acid on the amine nature and on the metal and polymer concentration was studied.
引用
收藏
页码:268 / 271
页数:4
相关论文
共 8 条
[1]   REACTIONS OF CARBON-DIOXIDE WITH CARBON CARBON BOND FORMATION CATALYZED BY TRANSITION-METAL COMPLEXES [J].
BRAUNSTEIN, P ;
MATT, D ;
NOBEL, D .
CHEMICAL REVIEWS, 1988, 88 (05) :747-764
[2]   POTENTIAL SOURCES OF CO2 AND THE OPTIONS FOR ITS LARGE-SCALE UTILIZATION NOW AND IN THE FUTURE [J].
EDWARDS, JH .
CATALYSIS TODAY, 1995, 23 (01) :59-66
[3]  
FARLA JCM, 1995, CLIMAT CHANGE, V29, P436
[4]   HOMOGENEOUS HYDROGENATION OF CARBON-DIOXIDE [J].
JESSOP, PG ;
IKARIYA, T ;
NOYORI, R .
CHEMICAL REVIEWS, 1995, 95 (02) :259-272
[5]   Two-phase Wacker oxidation of alkenes catalyzed by water-soluble macromolecular complexes of palladium [J].
Karakhanov, E ;
Filippova, T ;
Maximov, A ;
Predeina, V ;
Restakyan, A .
MACROMOLECULAR SYMPOSIA, 1998, 131 :87-94
[6]   A THEORETICAL-STUDY OF THE FORMATION OF CARBONIC-ACID FROM THE HYDRATION OF CARBON-DIOXIDE - A CASE OF ACTIVE SOLVENT CATALYSIS [J].
NGUYEN, MT ;
HA, TK .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (03) :599-602
[7]   Photo-induced generation of dihydrogen and reduction of carbon dioxide using transition metal complexes [J].
Sutin, N ;
Creutz, C ;
Fujita, E .
COMMENTS ON INORGANIC CHEMISTRY, 1997, 19 (02) :67-92
[8]  
Yin Xiaolong, 1995, Journal of Environmental Sciences (China), V7, P129