Simultaneous removal of NO and SO2 using vacuum ultraviolet light (VUV)/heat/peroxymonosulfate (PMS)

被引：161
作者：
Liu, Yangxian [1 ]
Wang, Yan [1 ]
Wang, Qian [1 ]
Pan, Jianfeng [1 ]
Zhang, Jun [2 ]
机构：
[1] Jiangsu Univ, Sch Energy & Power Engn, Zhenjiang 212013, Jiangsu, Peoples R China
[2] Southeast Univ, Key Lab Energy Thermal Convers & Control, Minist Educ, Nanjing 210096, Jiangsu, Peoples R China
来源：
CHEMOSPHERE | 2018年 / 190卷
基金：
中国博士后科学基金; 中国国家自然科学基金;
关键词：
Peroxymonosulfate (PMS); Vacuum ultraviolet light (VUV); SO2; NO; Sulfate free radical (SO4-center dot); Hydroxyl free radical ((OH)-O-center dot); SIMULATED FLUE-GAS; NITRIC-OXIDE; SULFUR-DIOXIDE; SIMULTANEOUS ABSORPTION; ELEMENTAL MERCURY; REACTION PATHWAYS; OXIDATION; KINETICS; HG-0; PEROXYMONOSULFATE;
D O I：
10.1016/j.chemosphere.2017.10.020
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
Simultaneous removal process of SO2 and NO from flue gas using vacuum ultraviolet light (VUV)/heat/peroxymonosulfate (PMS) in a VUV spraying reactor was proposed. The key influencing factors, active species, reaction products and mechanism of SO2 and NO simultaneous removal were investigated. The results show that vacuum ultraviolet light (185 nm) achieves the highest NO removal efficiency and yield of SO4-center dot and center dot OH under the same test conditions. NO removal is, enhanced at higher PMS concentration, light intensity and oxygen concentration, and is inhibited at higher NO concentration, SO2 concentration and solution pH. Solution temperature has a double impact on NO removal. CO2 concentration has no obvious effect on NO removal. SO4-center dot and center dot OH produced from VUV-activation of PMS play a leading role in NO removal. O-3 and center dot O produced from VUV-activation of O-2 also play an important role in NO removal. SO2 achieves complete removal under all experimental conditions due to its very high solubility in water and good reactivity. The highest simultaneous removal efficiency of SO2 and NO reaches 100% and 91.3%, respectively. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码：431 / 441
页数：11
相关论文
共 42 条
[1]   Aqueous absorption and oxidation of nitric oxide with oxone for the treatment of tail gases: Process feasibility, stoichiometry, reaction pathways, and absorption rate [J].
Adewuyi, YG ;
Owusu, SO .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2003, 42 (17) :4084-4100
[2]   Simultaneous Absorption and Oxidation of Nitric Oxide and Sulfur Dioxide by Aqueous Solutions of Sodium Persulfate Activated by Temperature [J].
Adewuyi, Yusuf G. ;
Sakyi, Nana Y. .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2013, 52 (33) :11702-11711
[3]   Simultaneous removal of SO2 and NO in a rotating drum biofilter coupled with complexing absorption by FeII(EDTA) [J].
Chen, Jun ;
Gu, Siyang ;
Zheng, Ji ;
Chen, Jianmeng .
BIOCHEMICAL ENGINEERING JOURNAL, 2016, 114 :90-96
[4]   Application of peroxymonosulfate and its activation methods for degradation of environmental organic pollutants: Review [J].
Ghanbari, Farshid ;
Moradi, Mahsa .
CHEMICAL ENGINEERING JOURNAL, 2017, 310 :41-62
[5]   Visible-light-induced photocatalytic oxidation of nitric oxide and sulfur dioxide: Discrete kinetics and mechanism [J].
Han, Yinghui ;
Zhang, Junjun ;
Zhao, Yi .
ENERGY, 2016, 103 :725-734
[6]   Removal of SO2 and NOx by Pulsed Corona Combined with in situ Ca(OH)2 Absorption [J].
Huang Liwei ;
Dang Yongxia .
CHINESE JOURNAL OF CHEMICAL ENGINEERING, 2011, 19 (03) :518-522
[7]   Simultaneous SO2 and NO removal using sorbents derived from rice husks: An optimisation study [J].
Lau, L. C. ;
Lee, K. T. ;
Mohamed, A. R. .
FUEL, 2011, 90 (05) :1811-1817
[8]  
Li Chong-jiu, 2015, Journal of Fuel Chemistry and Technology, V43, P1516, DOI 10.1016/S1872-5813(16)30004-4
[9]   Degradation of atenolol by UV/peroxymonosulfate: Kinetics, effect of operational, parameters and mechanism [J].
Liu, Xiaowei ;
Zhang, Tuqiao ;
Zhou, Yongchao ;
Fang, Lei ;
Shao, Yu .
CHEMOSPHERE, 2013, 93 (11) :2717-2724
[10]  
Liu Y.X., 2011, STUDY INTEGRATED DES, P10
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