Facile and Mild Process for Chemical Fixation of CO2 to 4-Methylene-1,3-oxazolidin-2-ones Under Solvent-Free Conditions

被引：10
作者：
Xu, Jingxiu [1 ]
Zhao, Jinwu [1 ]
Jia, Zhenbin [1 ]
Zhang, Jianhe [1 ]
机构：
[1] Guangdong Med Coll, Sch Pharm, Dongguan, Peoples R China
来源：
SYNTHETIC COMMUNICATIONS | 2011年 / 41卷 / 06期
关键词：
Carbon dioxide; chemical fixation; oxazolidinone; propargylic alcohol; solvent-free; ECO-FRIENDLY PROCESS; BETA-AMINO ALCOHOLS; CARBON-DIOXIDE; CHIRAL AUXILIARIES; OXAZOLIDINONES; CATALYSTS; EFFICIENT; 2-OXAZOLIDINONES; CARBONYLATION; COMPLEXES;
D O I：
10.1080/00397911003707014
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
[image omitted] 4-Methylene-1,3-oxazolidin-2-ones were prepared via the cycloadditon reaction of propargylic alcohols with primary amines and CO2 under atmospheric pressure at 60 degrees C in the absence of any additional solvent. This methodology affords an ecofriendly, mild, and easy approach to chemical fixation of CO2.
引用
收藏
页码：858 / 863
页数：6
相关论文
共 20 条
  • [1] 1,2-amino alcohols and their heterocyclic derivatives as chiral auxiliaries in asymmetric synthesis
    Ager, DJ
    Prakash, I
    Schaad, DR
    [J]. CHEMICAL REVIEWS, 1996, 96 (02) : 835 - 875
  • [2] BHALCHANDRA MB, 2004, GREEN CHEM, V6, P78
  • [3] Synthesis of cyclic ureas and urethanes from alkylene diamines and amino alcohols with pressurized carbon dioxide in the absence of catalysts
    Bhanage, BM
    Fujita, S
    Ikushima, Y
    Arai, M
    [J]. GREEN CHEMISTRY, 2003, 5 (03) : 340 - 342
  • [4] Making plastics from carbon dioxide:: Salen metal complexes as catalysts for the production of polycarbonates from epoxides and CO2
    Darensbourg, Donald J.
    [J]. CHEMICAL REVIEWS, 2007, 107 (06) : 2388 - 2410
  • [5] 2-OXAZOLIDONES
    DYEN, ME
    SWERN, D
    [J]. CHEMICAL REVIEWS, 1967, 67 (02) : 197 - &
  • [6] A SIMPLE SYNTHESIS OF OXAZOLIDINONES IN ONE-STEP FROM CARBON-DIOXIDE
    FOURNIER, J
    BRUNEAU, C
    DIXNEUF, PH
    [J]. TETRAHEDRON LETTERS, 1990, 31 (12) : 1721 - 1722
  • [7] Carbonylation of o-phenylenediamine and o-aminophenol with dimethyl carbonate using lead compounds as catalysts
    Fu, Y
    Baba, T
    Ono, Y
    [J]. JOURNAL OF CATALYSIS, 2001, 197 (01) : 91 - 97
  • [8] Ionic liquid as an efficient promoting medium for fixation of carbon dioxide: a clean method for the synthesis of 5-methylene-1,3-oxazolidin-2-ones from propargylic alcohols, amines, and carbon dioxide catalyzed by CUM under mild conditions
    Gu, YL
    Zhang, QH
    Duan, ZY
    Zhang, J
    Zhang, SG
    Deng, YQ
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (18) : 7376 - 7380
  • [9] An efficient and eco-friendly process for the conversion of carbon dioxide into oxazolones and oxazolidinones under Supercritical conditions
    Jiang, Huanfeng
    Zhao, Jinwu
    Wang, Azhong
    [J]. SYNTHESIS-STUTTGART, 2008, (05): : 763 - 769
  • [10] Synthesis of 2-oxazolidinones by salen-Co-complexes catalyzed oxidative carbonylation of β-amino alcohols
    Liu, Jian-Ming
    Peng, Xin-Gao
    Liu, Jian-Hua
    Zheng, Shu-Zhan
    Sun, Wei
    Xia, Chun-Gu
    [J]. TETRAHEDRON LETTERS, 2007, 48 (06) : 929 - 932
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