Green one-step synthesis of SnS2 quantum dots/S-doped reduced graphene oxide composite for superior lithium storage

被引:9
作者
Zhang, Bin [1 ]
Zhou, Xiaozhong [1 ]
Peng, Hui [1 ]
Zhu, Chunyan [1 ]
Wang, Wuqiang [1 ]
Lei, Ziqiang [1 ]
机构
[1] Northwest Normal Univ, Coll Chem & Chem Engn, Key Lab Ecofunct Polymer Mat Minist Educ, Key Lab Ecoenvironm Polymer Mat Gansu Prov, Lanzhou 730070, Gansu, Peoples R China
基金
中国国家自然科学基金;
关键词
SnS2; Reduced graphene oxide; Quantum dots; Lithium-ion battery; HIGH-PERFORMANCE ANODE; ION BATTERIES; LI-ION; CYCLING STABILITY; HIGH-CAPACITY; SODIUM; NANOSHEETS; HETEROSTRUCTURES; AEROGELS; SHEETS;
D O I
10.1007/s11581-019-03175-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
SnS2 has been considered as one of the most potential anode materials for lithium storage due to its high theoretical capacity. However, the SnS2-based electrodes still suffer from unsatisfied electrochemical lithium-storage performance due to the intrinsic poor conductivity, large volume change during cycles, and great irreversibility of the initial conversion reactions. Herein, SnS2 quantum dots (QDs) are uniform fixed in S-doped reduced graphene oxide (rGO) nanosheets or nanoscrolls by a simple green one-step hydrothermal method, which deliver superior lithium-storage performance, such as a high initial reversible capacity of 1151 mA h g(-1) at a current density of 200 mA g(-1), high capacity retention of 87.7% after 300 cycles at 500 mA g(-1), and superior rate capacity of 314 mA h g(-1) at 5000 mA g(-1).
引用
收藏
页码:95 / 103
页数:9
相关论文
共 36 条
[1]   Vanadium Nitride Nanowire Supported SnS2 Nanosheets with High Reversible Capacity as Anode Material for Lithium Ion Batteries [J].
Balogun, Muhammad-Sadeeq ;
Qiu, Weitao ;
Jian, Junhua ;
Huang, Yongchao ;
Luo, Yang ;
Yang, Hao ;
Liang, Chaolun ;
Lu, Xihong ;
Tong, Yexiang .
ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (41) :23205-23215
[2]   Tin Disulfide Nanoflowers versus Nanosheets as Anodes in Lithium-ion Batteries: How the Nanostructure Controls Performance [J].
Bhaskar, Akkisetty ;
Deepa, Melepurath ;
Rao, T. Narasinga .
ELECTROCHIMICA ACTA, 2015, 184 :239-249
[3]   MoS2-on-MXene Heterostructures as Highly Reversible Anode Materials for Lithium-Ion Batteries [J].
Chen, Chi ;
Xie, Xiuqiang ;
Anasori, Babak ;
Sarycheva, Asya ;
Makaryan, Taron ;
Zhao, Mengqiang ;
Urbankowski, Patrick ;
Miao, Ling ;
Jiang, Jianjun ;
Gogotsi, Yury .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (07) :1846-1850
[4]   Revealing Pseudocapacitive Mechanisms of Metal Dichalcogenide SnS2/Graphene-CNT Aerogels for High-Energy Na Hybrid Capacitors [J].
Cui, Jiang ;
Yao, Shanshan ;
Lu, Ziheng ;
Huang, Jian-Qiu ;
Chong, Woon Gie ;
Ciucci, Francesco ;
Kim, Jang-Kyo .
ADVANCED ENERGY MATERIALS, 2018, 8 (10)
[5]   Promising Dual-Doped Graphene Aerogel/SnS2 Nanocrystal Building High Performance Sodium Ion Batteries [J].
Fan, Linlin ;
Li, Xifei ;
Song, Xiaosheng ;
Hu, Nana ;
Xiong, Dongbin ;
Koo, Alicia ;
Sun, Xueliang .
ACS APPLIED MATERIALS & INTERFACES, 2018, 10 (03) :2637-2648
[6]   Challenges for Rechargeable Li Batteries [J].
Goodenough, John B. ;
Kim, Youngsik .
CHEMISTRY OF MATERIALS, 2010, 22 (03) :587-603
[7]   Inhibiting grain coarsening and inducing oxygen vacancies: the roles of Mn in achieving a highly reversible conversion reaction and a long life SnO2-Mn-graphite ternary anode [J].
Hu, Renzong ;
Ouyang, Yunpeng ;
Liang, Tao ;
Tang, Xin ;
Yuan, Bin ;
Liu, Jun ;
Zhang, Lei ;
Yang, Lichun ;
Zhu, Min .
ENERGY & ENVIRONMENTAL SCIENCE, 2017, 10 (09) :2017-2029
[8]   Stabilizing the Nanostructure of SnO2 Anodes by Transition Metals: A Route to Achieve High Initial Coulombic Efficiency and Stable Capacities for Lithium Storage [J].
Hu, Renzong ;
Ouyang, Yunpeng ;
Liang, Tao ;
Wang, Hui ;
Liu, Jun ;
Chen, Jun ;
Yang, Chenghao ;
Yang, Liuchun ;
Zhu, Min .
ADVANCED MATERIALS, 2017, 29 (13)
[9]   PREPARATION OF GRAPHITIC OXIDE [J].
HUMMERS, WS ;
OFFEMAN, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339
[10]   Ultrasmall SnS2 nanoparticles anchored on well-distributed nitrogen-doped graphene sheets for Li-ion and Na-ion batteries [J].
Jiang, Yong ;
Feng, Yazhi ;
Xi, Baojuan ;
Kai, Shuangshuang ;
Mi, Kan ;
Feng, Jinkui ;
Zhang, Junhao ;
Xiong, Shenglin .
JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (27) :10719-10726