Ionothermal Synthesis of an Aluminophosphate Molecular Sieve with 20-Ring Pore Openings

被引：115

作者：

Wei, Ying ^{[1
,2
]}

Tian, Zhijian ^{[1
]}

Gies, Hermann ^{[3
]}

Xu, Renshun ^{[1
,2
]}

Ma, Huaijun ^{[1
]}

Pei, Renyan ^{[1
,2
]}

Zhang, Weiping ^{[1
]}

Xu, Yunpeng ^{[1
]}

Wang, Lei ^{[1
]}

Li, Keda ^{[1
,2
]}

Wang, Bingchun ^{[1
]}

Wen, Guodong ^{[1
,2
]}

Lin, Liwu ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

[3] Ruhr Univ Bochum, Inst Geol Mineral & Geophys, D-44780 Bochum, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 31期

基金：

中国国家自然科学基金;

关键词：

aluminophosphates; -CLO structure; extralarge pores; ionic liquids; zeolite analogues; METAL-ORGANIC FRAMEWORKS; IONIC LIQUIDS; ZEOLITE; CLOVERITE; RINGS;

D O I：

10.1002/anie.201000320

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Figure Presented Open for business: The first aluminophosphate molecular sieve with 20-ring pore openings has been synthesized ionothermally using a co-structure-directing agent (see figure; H white, C turquoise, N blue). The new material has a -CLO framework and excellent stability in comparison to the QaPO4 analogue cloverite. These characteristics indicate its potential applications in separation, catalysis, and gas storage. © 2010 Wiley-VCH Verlag GmbH & Co. KCaA,.

引用

页码：5367 / 5370

页数：4

共 32 条

[1]

Baerlocher Ch., 2007, ATLAS ZEOLITE STRUCT, V6th

[2] EVIDENCE FOR STRONG ACIDITY OF THE MOLECULAR-SIEVE CLOVERITE [J].