(-)-β-Pinene-based π-Allylpalladium Complex-Catalyzed Asymmetric Allylation of Bis-Imines

被引：0

作者：

Fernandes, Rodney A. ^{[1
]}

Nallasivam, Jothi L. ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Mumbai 400076, Maharashtra, India

来源：

CHEMISTRYSELECT | 2020年 / 5卷 / 27期

关键词：

Allylation; pi-Allylpalladium; Asymmetric synthesis; Catalysis; Homoallylamines; OLEFIN-PALLADIUMCHLORID-KOMPLEXE; SYNTHETIC REACTIONS; ZUR KONSTITUTION; FUNCTIONALIZATION; ALKYLATION; BUTADIENE; LIGAND; COPPER;

D O I：

10.1002/slct.202002599

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(-)-beta-Pinene-based eta(3)-pi-allylpalladium complex has shown the efficacy in the catalytic asymmetric allylation of para- andmeta-xylene spaced bis-arylimines. The complex has catalyzed asymmetric allylation of various bis-imines in the presence of allyltributylstannane and two equivalents of water to furnish chiral bis-homoallylamines in moderate to good yields (up to 70%) and enantioselectivities up to 98.6 : 1.4 er.

引用

页码：8301 / 8304

页数：4

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