Diaquabis(4-hydroxybenzoato-κO)(1,10-phenan-throline-κ2N,N′)cobalt(II) monohydrate

被引:5
作者
Su, JR
Gu, JM
Xu, DJ [1 ]
机构
[1] Zhejiang Univ, Dept Chem, Hangzhou, Peoples R China
[2] Zhejiang Univ, Measurement Ctr, Hangzhou, Peoples R China
关键词
D O I
10.1107/S1600536805013000
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title complex, [Co(C7H5O3)(2)(C12H8N2)(H2O)(2)](H2O)-H-., displays a distorted octahedral coordination geometry about the Co-II atom, involving two 4-hydroxybenzoate anions, one 1,10-phenanthroline ( phen) molecule and two water molecules. The face-to-face distance of 3.420 ( 5) angstrom between partially overlapped parallel phen rings reflects a pi-pi stacking interaction between neighboring Co-II complex molecules. A network of O-(HO)-O-... hydrogen bonds helps to stabilize the crystal packing.
引用
收藏
页码:M1033 / M1035
页数:3
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