Mn3O4 Nanosheet and GNS-Mn3O4 Composite as High-Performance Anode Materials for Lithium-Ion Batteries

被引:0
作者
Sun, Weiwei [1 ]
Yu, Zhiqiang [1 ]
Lv, Li-Ping [1 ]
Xu, Yi [1 ]
Liu, Hao [1 ,2 ]
Wang, Guoxiu [2 ]
Wang, Yong [1 ]
机构
[1] Shanghai Univ, Sch Environm & Chem Engn, Dept Chem Engn, Shangda Rd 99, Shanghai 200444, Peoples R China
[2] Univ Technol Sydney, Ctr Clean Energy Technol, Sch Math & Phys Sci, Sydney, NSW 2007, Australia
基金
中国国家自然科学基金;
关键词
Mn3O4; Graphene; Nanoparticle; Lithium-ion battery; GRAPHENE OXIDE HYBRID; MN3O4/GRAPHENE COMPOSITES; HYDROTHERMAL SYNTHESIS; FACILE SYNTHESIS; NANOPARTICLES; CAPACITY; ELECTRODES; NANOCOMPOSITE; DERIVATION; NANOROD;
D O I
10.1007/s13369-017-2611-2
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Nanostructured transitional metal oxides have received more and more attention as the electrode materials for lithium-ion batteries to achieve high specific capacity and good safety performance. In this paper, a graphene nanosheet-supported nanoparticles (-GNS) composite, as well as nanosheet, were synthesized via a facile hydrothermal method. The -GNS composite exhibits good electrochemical performances with high reversible specific capacity (an initial charge capacity of 969 mAh at 93.6 mA ), good cycling stability (a retained capacity of 646 mAh after 60 cycles) and rate capability when used as the anode material for LIBs. The enhanced electrochemical performance could be attributed to the nanoscaled particles of , the buffer and confine effects of graphene nanosheets (GNSs) and the distinctive synergistic effect between two components of GNS and metal oxides.
引用
收藏
页码:4281 / 4289
页数:9
相关论文
共 52 条
[1]  
[Anonymous], PLOS ONE
[2]   Building better batteries [J].
Armand, M. ;
Tarascon, J. -M. .
NATURE, 2008, 451 (7179) :652-657
[3]  
Brandt K., 2006, SOLID STATE IONICS, V69, P173
[4]   Facile synthesis of graphene-supported mesoporous Mn3O4 nanosheets with a high-performance in Li-ion batteries [J].
Chen, Chao ;
Jian, Hong ;
Fu, Xinxin ;
Ren, Zhimin ;
Yan, Mi ;
Qian, Guodong ;
Wang, Zhiyu .
RSC ADVANCES, 2014, 4 (11) :5367-5370
[5]   Self-assembly of stacked layers of Mn3O4 nanosheets using a scalable chemical strategy for enhanced, flexible, electrochemical energy storage [J].
Dubal, Deepak P. ;
Holze, Rudolf .
JOURNAL OF POWER SOURCES, 2013, 238 :274-282
[6]   One-pot hydrothermal synthesis of Mn3O4/graphene nanocomposite for supercapacitors [J].
Fan, Yafei ;
Zhang, Xudong ;
Liu, Yushan ;
Cai, Qiang ;
Zhang, Jianmin .
MATERIALS LETTERS, 2013, 95 :153-156
[7]   Low-temperature synthesis of Mn3O4 hollow-tetrakaidecahedrons and their application in electrochemical capacitors [J].
Fang, Ming ;
Tan, Xiaoli ;
Liu, Mao ;
Kang, Shenghong ;
Hu, Xiaoye ;
Zhang, Lide .
CRYSTENGCOMM, 2011, 13 (15) :4915-4920
[8]   Electrode reactions of manganese oxides for secondary lithium batteries [J].
Fang, Xiangpeng ;
Lu, Xia ;
Guo, Xianwei ;
Mao, Ya ;
Hu, Yong-Sheng ;
Wang, Jiazhao ;
Wang, Zhaoxiang ;
Wu, Feng ;
Liu, Huakun ;
Chen, Liquan .
ELECTROCHEMISTRY COMMUNICATIONS, 2010, 12 (11) :1520-1523
[9]   Spongelike Nanosized Mn3O4 as a High-Capacity Anode Material for Rechargeable Lithium Batteries [J].
Gao, Jie ;
Lowe, Michael A. ;
Abruna, Hector D. .
CHEMISTRY OF MATERIALS, 2011, 23 (13) :3223-3227
[10]   Graphene-Wrapped CoS Nanoparticles for High-Capacity Lithium-Ion Storage [J].
Gu, Yan ;
Xu, Yi ;
Wang, Yong .
ACS APPLIED MATERIALS & INTERFACES, 2013, 5 (03) :801-806