Design and Realization of White Quantum Dot Light-Emitting Electrochemical Cell Hybrid Devices

被引:25
作者
Frohleiks, Julia [1 ,2 ,3 ]
Gellner, Sandra [1 ,2 ,3 ]
Wepfer, Svenja [1 ,2 ,3 ]
Bacher, Gerd [2 ,3 ]
Nannen, Ekaterina [1 ,2 ,3 ]
机构
[1] Univ Duisburg Essen, Res Grp Solid State Lighting, NanoEnergieTechnikZentrum, Carl Benz Str 199, D-47057 Duisburg, Germany
[2] Univ Duisburg Essen, Werkstoffe Elektrotech, Bismarckstr 81, D-47057 Duisburg, Germany
[3] Univ Duisburg Essen, CENIDE, Bismarckstr 81, D-47057 Duisburg, Germany
关键词
light-emitting hybrid devices; quantum dots; light-emitting electrochemical cells; white light emitters; iTMC; TRANSITION-METAL COMPLEX; CHARGE INJECTION; HIGHLY EFFICIENT; BLUE-GREEN; POLYMER; ELECTROLUMINESCENCE; TRANSPORT; EMISSION; BRIGHT;
D O I
10.1021/acsami.8b15100
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The simple device architecture as well as the solution-based processing makes light-emitting electrochemical cells (LECs) a promising device concept for large-area flexible lighting solutions. The lack of deep-blue emitters, which are, at the same time, efficient, bright, and long-term stable, complementary to the wide variety of yellow-orange emitting LECs, hampers the creation of white LECs. We present a hybrid device concept for the realization of white light emission by combining blue colloidal quantum dots (QDs) and an Ir-based ionic transition-metal complex (iTMC) LEC in a new type of white QD-LEC hybrid device (QLEC). By careful arrangement of the active layers, we yield light emission from both the blue QDs and the yellow iTMC emitter already at voltages below 3 V. The QLEC devices show homogeneous white light emission with high color rendering index (up to 80), luminance levels above 850 cd m(-2), and a maximum external quantum efficiency greater than 0.2%.
引用
收藏
页码:42637 / 42646
页数:10
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