Hydroformylation of hex-1-ene in supercritical carbon dioxide catalysed by rhodium trialkylphosphine complexes

被引：63

作者：

Bach, I ^{[1
]}

Cole-Hamilton, DJ ^{[1
]}

机构：

[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 14期

关键词：

D O I：

10.1039/a803855d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Triethylphosphine complexes of rhodium catalyse the hydroformylation of hex-l-ene in supercritical carbon dioxide at rates similar to those obtained in toluene, but with a slightly improved n:i ratio; using trioctylphosphine, much lower rates are observed.

引用

页码：1463 / 1464

页数：2

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