Metal-free Dehydrogenative Isoquinolone Synthesis

被引:14
作者
Jin, Rongwei [1 ]
Patureau, Frederic W. [1 ]
机构
[1] Kaiserslautern Univ Technol, Dept Chem, D-67663 Kaiserslautern, Germany
关键词
C-H activation; dehydrogenative Friedel-Crafts reactions; hypervalent iodine; organocatalysis; transition metals; C-H; OXIDATIVE CYCLOADDITION; MEDIATED AZIRIDINATION; O BOND; ALKYNES; ACTIVATION; BENZAMIDES; AMIDES; CATALYSIS; ALKENES;
D O I
10.1002/cctc.201402704
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We discuss Manna and Antonchick's metal-free isoquinolone synthesis through the dehydrogenative condensation of benzamides with alkynes and what it means for the fields of C-H functionalization and organic synthesis. DG=Directing group, E=electrophile. (Graph Presented) © 2015 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:223 / 225
页数:3
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