Structural and Electronic Study of an Amorphous MoS3 Hydrogen-Generation Catalyst on a Quantum-Controlled Photosensitizer

被引：185
作者：
Tang, Ming L. [1 ]
Grauer, David C. [1 ]
Lassalle-Kaiser, Benedikt
Yachandra, Vittal K.
Amirav, Lilac [1 ]
Long, Jeffrey R. [1 ]
Yano, Junko
Alivisatos, A. Paul [1 ]
机构：
[1] Univ Calif Berkeley, Dept Chem, LBNL, Berkeley, CA 94720 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 43期
关键词：
hydrogen; molybdenum; nanoparticles; photochemistry; X-ray absorption spectroscopy; VISIBLE-LIGHT; H-2; EVOLUTION; WATER; MOLYBDENUM; PHOTOCATALYST; ABSORPTION; HYDRODESULFURIZATION; ELECTROCATALYSTS; HETEROSTRUCTURES; SPECTROSCOPY;
D O I：
10.1002/anie.201104412
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Light-water reactor: An amorphous molybdenum sulfide species structurally similar to reduced MoS3 is shown to be photocatalytically active for hydrogen generation from H2O with visible light (see picture; TEOA=triethanolamine). Thermally deposited in one step, MoS3 is photosensitized by quantum-controlled semiconductor nanocrystals that serve as model systems for the photophysics of solar fuel generation. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：10203 / 10207
页数：5
相关论文
共 38 条
  • [1] Photocatalytic Hydrogen Production with Tunable Nanorod Heterostructures
    Amirav, Lilac
    Alivisatos, A. Paul
    [J]. JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2010, 1 (07): : 1051 - 1054
  • [2] Molybdenum-sulfur dimers as electrocatalysts for the production of hydrogen at low overpotentials
    Appel, AM
    DuBois, DL
    DuBois, MR
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (36) : 12717 - 12726
  • [3] Synthesis and micrometer-scale assembly of colloidal CdSe/CdS nanorods prepared by a seeded growth approach
    Carbone, Luigi
    Nobile, Concetta
    De Giorgi, Milena
    Sala, Fabio Delia
    Morello, Giovanni
    Pompa, Pierpaolo
    Hytch, Martin
    Snoeck, Etienne
    Fiore, Angela
    Franchini, Isabella R.
    Nadasan, Monica
    Silvestre, Albert F.
    Chiodo, Letizia
    Kudera, Stefan
    Cingolani, Roberto
    Krahne, Roman
    Manna, Liberato
    [J]. NANO LETTERS, 2007, 7 (10) : 2942 - 2950
  • [4] Semiconductor-based Photocatalytic Hydrogen Generation
    Chen, Xiaobo
    Shen, Shaohua
    Guo, Liejin
    Mao, Samuel S.
    [J]. CHEMICAL REVIEWS, 2010, 110 (11) : 6503 - 6570
  • [5] EXAFS STUDIES OF AMORPHOUS MOLYBDENUM AND TUNGSTEN TRISULFIDES AND TRISELENIDES
    CRAMER, SP
    LIANG, KS
    JACOBSON, AJ
    CHANG, CH
    CHIANELLI, RR
    [J]. INORGANIC CHEMISTRY, 1984, 23 (09) : 1215 - 1221
  • [6] Alternative energy technologies
    Dresselhaus, MS
    Thomas, IL
    [J]. NATURE, 2001, 414 (6861) : 332 - 337
  • [7] CdSe-MoS2: A Quantum Size-Confined Photocatalyst for Hydrogen Evolution from Water under Visible Light
    Frame, F. Andrew
    Osterloh, Frank E.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (23) : 10628 - 10633
  • [8] Preparation and characterization of molybdenum sulfide supported on β-zeolites obtained from [Mo3S4(H2O)9]4+ precursor
    Hedoire, Claude-Emmanuel
    Cadot, Emmanuel
    Villain, Françoise
    Davidson, Anne
    Louis, Catherine
    Breysse, Michele
    [J]. APPLIED CATALYSIS A-GENERAL, 2006, 306 : 165 - 174
  • [9] MO K-EDGE EXAFS AND S K-EDGE ABSORPTION STUDIES OF THE AMORPHOUS MOLYBDENUM SULFIDES MOS4.7, MOS3, AND MOS3-CENTER-DOT-NH(2)0 (N-SIMILAR-TO-2)
    HIBBLE, SJ
    RICE, DA
    PICKUP, DM
    BEER, MP
    [J]. INORGANIC CHEMISTRY, 1995, 34 (21) : 5109 - 5113
  • [10] Modeling the structure of amorphous MoS3:: A neutron diffraction and reverse Monte Carlo study
    Hibble, SJ
    Wood, GB
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (03) : 959 - 965
1234