Development and characterization of a novel silicon-based glassy composite as an anode material for Li-ion batteries

被引：15
作者：
Wang, Xiuyan [1 ]
Wen, Zhaoyin [1 ]
Liu, Yu [1 ]
Huang, Ying [1 ]
Wen, Ting-Lian [1 ]
机构：
[1] Chinese Acad Sci, CAS Key Lab Mat Energy Convers, Shanghai Inst Ceram, Shanghai 200050, Peoples R China
来源：
SOLID STATE IONICS | 2011年 / 192卷 / 01期
关键词：
Silicon-based composite; Anode; Glassy matrices; HEMM; Li-ion batteries; RECHARGEABLE LITHIUM BATTERIES; ELECTROCHEMICAL CHARACTERIZATION; NEGATIVE ELECTRODES; NANOSIZED SILICON; IN-SITU; TIN; OXIDES;
D O I：
10.1016/j.ssi.2010.03.008
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A novel silicon-based glassy composite anode material with high initial coulombic efficiency and long cycling performance for lithium-ion batteries was synthesized by a wet mechanochemical reduction method. The in Situ formed Si particles with size of 5-10 nm were uniformly distributed in the glassy matrices formed by B(2)O(3) and P(2)O(5). The as-prepared composite electrode revealed an initial charge and discharge capacity of 432.7 and 514.4 mAh g(-1) respectively, with an initial coulombic efficiency of 84%. After 100 cycles, the reversible capacity retention rate was still up to 97%, meaning a favorable cycling stability. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：330 / 334
页数：5
相关论文
共 50 条
  • [21] Deposition of silver nanoparticles into silicon/carbon composite as a high-performance anode material for Li-ion batteries
    Xianhua Hou
    Miao Zhang
    Jiyun Wang
    Shejun Hu
    Xiang Liu
    Journal of Solid State Electrochemistry, 2015, 19 : 3595 - 3604
  • [22] Deposition of silver nanoparticles into silicon/carbon composite as a high-performance anode material for Li-ion batteries
    Hou, Xianhua
    Zhang, Miao
    Wang, Jiyun
    Hu, Shejun
    Liu, Xiang
    JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2015, 19 (12) : 3595 - 3604
  • [23] Tin Phosphite SnHPO3 a New Anode Material for Li-ion Batteries
    Idrissi, Siham
    Edfouf, Zineb
    Benabdallah, Omar
    Lallaoui, Abdelfettah
    El Moursli, Fouzia Cherkaoui
    2018 6TH INTERNATIONAL RENEWABLE AND SUSTAINABLE ENERGY CONFERENCE (IRSEC), 2018, : 1062 - 1066
  • [24] Substoichiometric Silicon Nitride -An Anode Material for Li-ion Batteries Promising High Stability and High Capacity
    Ulvestad, Asbjorn
    Andersen, Hanne F.
    Jensen, Ingvild J. T.
    Mongstad, Trygve T.
    Maehlen, Jan Petter
    Prytz, Oystein
    Kirkengen, Martin
    SCIENTIFIC REPORTS, 2018, 8
  • [25] Highly adhesive and stretchable binder for silicon-based anodes in Li-ion batteries
    Tang, Ruixian
    Zheng, Xiao
    Zhang, Yu
    Ma, Lei
    Dong, Yanru
    Kong, Guolong
    Wei, Liangming
    IONICS, 2020, 26 (12) : 5889 - 5896
  • [26] An alternative carbon source of silicon-based anode material for lithium ion batteries
    Zhou, Rong
    Guo, Huajun
    Yang, Yong
    Wang, Zhixing
    Li, Xinhai
    Zhou, Yu
    POWDER TECHNOLOGY, 2016, 295 : 296 - 302
  • [27] Synthesis of spherical nano tin encapsulated pyrolytic polyacrylonitrile composite anode material for Li-ion batteries
    He, Xiangming
    Pu, Weihua
    Wang, Li
    Ren, Jianguo
    Jiang, Changyin
    Wan, Chunrong
    SOLID STATE IONICS, 2007, 178 (11-12) : 833 - 836
  • [28] Manganese monoxide/titanium nitride composite as high performance anode material for rechargeable Li-ion batteries
    Xu, Gaojie
    Zhang, Lixue
    Guo, Chaowei
    Gu, Lin
    Wang, Xiaogang
    Han, Pengxian
    Zhang, Kejun
    Zhang, Chuanjian
    Cui, Guanglei
    ELECTROCHIMICA ACTA, 2012, 85 : 345 - 351
  • [29] Development of nanocomposites for anode materials in Li-ion batteries
    Ochs, Rolf
    Szabo, Dorothee Vinga
    Schlabach, Sabine
    Becker, Sebastian
    Indris, Sylvio
    PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2011, 208 (02): : 471 - 473
  • [30] NbSb2 as an anode material for Li-ion batteries
    Reddy, M. Anji
    Varadaraju, U. V.
    JOURNAL OF POWER SOURCES, 2006, 159 (01) : 336 - 339
12345