Novel organosulfur donors containing hydroxy functionalities: synthesis of bis[2,2-bis(hydroxymethyl)propane-1,3-diyldithio]tetrathiafulvalene and related materials

被引:25
作者
Ozturk, T
Saygili, N
Ozkara, S
Pilkington, M
Rice, CR
Tranter, DA
Turksoy, F
Wallis, JD
机构
[1] TUBITAK Marmara Res Ctr, Dept Chem, TR-41470 Grebze Kocaeli, Turkey
[2] Nottingham Trent Univ, Dept Chem & Phys, Nottingham NG11 8NS, England
[3] Tech Univ Istanbul, Dept Chem Phys, Istanbul, Turkey
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 2001年 / 04期
基金
美国国家卫生研究院;
关键词
D O I
10.1039/b007660k
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The synthesis of four novel organosulfur donors carrying two or more hydroxymethyl groups are described. TTF nuclei are fused to 1,4-dithiepine and/or 1,4-dithiine rings and in two cases both outer rings carry functionality capable of introducing hydrogen bonding; for the two chiral organosulfur donor molecules both racemic and enantiopure forms are prepared.
引用
收藏
页码:407 / 414
页数:8
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