Cationic alkylzirconium complexes based on a tridentate diamide ligand: New alkene polymerization catalysts

被引：331

作者：

Horton, AD

DeWith, J

vanderLinden, AJ

vandeWeg, H

机构：

[1] Shell Res. Technol. Ctr., Amsterdam, 1030 BN Amsterdam

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 12期

关键词：

D O I：

10.1021/om960073k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Alkyl abstraction from {Me(3)SiN(CH(2)CH(2)NSiMe(3))(2)}ZrR(2) (N(3)ZrR(2); R = CH(2)Ph, Me) using B(C6F5)(3) affords cationic alkyl complexes stabilized by a diamide ligand. The ionic eta(2)-benzyl adduct decomposes slowly to give a cationic cyclometalation product, which coordinates the [PhCH(2)B(C6F5)(3)](-) anioin; the methyl cation coordinates the anion [MeB(C6F5)(3)](-) via a Zr...Me-B interaction. The complexes exhibit moderate ethene polymerization activity.

引用

页码：2672 / 2674

页数：3

共 31 条

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