Controlled synthesis of flower-like In2O3 microrods and their highly improved selectivity toward ethanol

In this study, well-defined, flower-like In2O3 microrods were successfully synthesized by a facile one-step hydrothermal method and subsequent calcination. Various techniques such as scanning electron microscopy (SEM), X-ray diffraction (XRD), transmission electron microscopy (TEM), and N-2 adsorption -desorption analyses were employed to clarify the feature of as-prepared product, including morphology, crystal structure and BET surface area. Appreciable control on the morphology of as -synthesized In2O3 samples was attained by altering the weight ratio of glucose and urea. The results show that the flower-like In2O3 microrods are formed in presence of glucose and urea, owing to the synergistic effect of the template role of glucose carbon spheres and Ostwald ripening under an alkaline environment. Moreover, the ethanol gas sensing properties of the flower-like In2O3 microrods were further investigated. Because of the structural merits including porosity and easily penetrable multiple rods, the sensor based on these flower-like In2O3 microrods exhibited superior sensitivity toward ethanol with a limit of detection lower to 1 ppm. In addition, improved selectivity to ethanol of this sensor is also demonstrated in other interfering gases, including formaldehyde, methanol, toluene, acetone, carbon oxides (CO) and Hydrogen (H-2). Also, the ethanol sensor displays a good repeatability. These results thereby demonstrate a potential application in a gas sensor for detecting ethanol vapor. (C) 2016 Elsevier B.V. All rights reserved.