Red emission from Eu-doped GaN luminescent films grown by metalorganic chemical vapor deposition

被引:51
作者
Pan, M [1 ]
Steckl, AJ [1 ]
机构
[1] Univ Cincinnati, Nanoelect Lab, Cincinnati, OH 45221 USA
关键词
D O I
10.1063/1.1590738
中图分类号
O59 [应用物理学];
学科分类号
摘要
Bright red emission has been obtained at room temperature from Eu-doped GaN films pumped by 325 nm HeCd laser. The luminescent films were grown by metalorganic chemical vapor deposition on GaN/Al2O3 substrates. Trimethylgallium (TMGa), ammonia (NH3), and europium 2,2,4,4-tetramethyl-3,5-heptanedionate were used as sources for Ga, N, and Eu dopant, respectively. The influence of the V/III ratio during growth on the photoluminescence (PL) intensity has been studied using a fixed TMGa flow rate of 92 mumol/min and varying the NH3 flow rate. The film growth rate (similar to2 mum/h) is nearly constant with V/III ratio over the range from similar to30 to similar to1000. The Eu incorporation in GaN films was found to decrease with increasing V/III ratio. The Eu PL intensity (normalized to the Eu concentration! exhibited a maximum at a V/III ratio of similar to100. (C) 2003 American Institute of Physics.
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页码:9 / 11
页数:3
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