Electrodeposition of cobalt-chromium alloys from cobalt chloride-N-(n-butyl)pyridinium chloride molten salt

被引:0
作者
Ali, MR [1 ]
Nishikata, A [1 ]
Tsuru, T [1 ]
机构
[1] Tokyo Inst Technol, Dept Met & Ceram Sci, Meguro Ku, Tokyo 152, Japan
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中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Electrodeposition of cobalt-chromium alloys of different compositions (up to 14 at% Cr) has been carried out onto copper cathode by the pulse potential and the pulse current methods from cobalt chloride-N-(n-butyl)pyridinium chloride (BPC) molten salt containing chromium(II) chloride at 110 degreesC. The magnetic properties of the deposited cobalt-chromium alloys have been investigated. The magnetic polarization of the deposited cobalt-chromium alloys at high fields decreases with the increase of chromium content in the deposit except Co-1.22 at% Cr alloy, with maximum magnetic polarization than the bulk cobalt. The cathodic current efficiency for the deposition of alloy is about 99 %.
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页码:44 / 50
页数:7
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