Applications of luminescent transition platinum group metal complexes to sensor technology and molecular probes

被引：256
作者：
Demas, JN [1 ]
DeGraff, BA
机构：
[1] Univ Virginia, Dept Chem, Charlottesville, VA 22904 USA
[2] James Madison Univ, Dept Chem, Harrisonburg, VA 22807 USA
来源：
COORDINATION CHEMISTRY REVIEWS | 2001年 / 211卷
基金：
美国国家科学基金会;
关键词：
luminescence; sensors; oxygen; pH; molecular probes;
D O I：
10.1016/S0010-8545(00)00278-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Luminescent transition metal complexes are currently revolutionizing many areas of photochemistry and photophysics. In particular, they are proving useful as molecular probes and sensors. We discuss the design consideration in producing useful sensors and probes. As we show, complexes are amenable to rational design. Applications of inorganic complexes to a variety of sensor technologies are discussed. In addition, problem areas such as sensor-support interactions are covered. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：317 / 351
页数：35
相关论文
共 97 条
[1]  
[Anonymous], 1983, EXCITED STATE LIFETI
[2]   EXCIPLEXES OF RUTHENIUM(II) ALPHA-DIIMINE COMPLEXES WITH SILVER(I) [J].
AYALA, NP ;
DEMAS, JN ;
DEGRAFF, BA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (05) :1523-1529
[3]   DETERMINATION OF OXYGEN CONCENTRATIONS BY LUMINESCENCE QUENCHING OF A POLYMER-IMMOBILIZED TRANSITION-METAL COMPLEX [J].
BACON, JR ;
DEMAS, JN .
ANALYTICAL CHEMISTRY, 1987, 59 (23) :2780-2785
[4]   SENSING OXYGEN THROUGH SKIN USING A RED DIODE-LASER AND FLUORESCENCE LIFETIMES [J].
BAMBOT, SB ;
RAO, G ;
ROMAULD, M ;
CARTER, GM ;
SIPIOR, J ;
TERPETCHNIG, E ;
LAKOWICZ, JR .
BIOSENSORS & BIOELECTRONICS, 1995, 10 (6-7) :643-652
[5]   CHIRAL PROBES FOR THE HANDEDNESS OF DNA HELICES - ENANTIOMERS OF TRIS(4,7-DIPHENYLPHENANTHROLINE)RUTHENIUM(II) [J].
BARTON, JK ;
BASILE, LA ;
DANISHEFSKY, A ;
ALEXANDRESCU, A .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA-BIOLOGICAL SCIENCES, 1984, 81 (07) :1961-1965
[6]   METALS AND DNA - MOLECULAR LEFT-HANDED COMPLEMENTS [J].
BARTON, JK .
SCIENCE, 1986, 233 (4765) :727-734
[7]   PHOTOPHYSICS AND PHOTOCHEMISTRY OF OXYGEN SENSORS BASED ON LUMINESCENT TRANSITION-METAL COMPLEXES [J].
CARRAWAY, ER ;
DEMAS, JN ;
DEGRAFF, BA ;
BACON, JR .
ANALYTICAL CHEMISTRY, 1991, 63 (04) :337-342
[8]   APPLICATION OF THE ENERGY-GAP LAW TO NONRADIATIVE, EXCITED-STATE DECAY [J].
CASPAR, JV ;
MEYER, TJ .
JOURNAL OF PHYSICAL CHEMISTRY, 1983, 87 (06) :952-957
[9]   SYNTHETIC ROUTES TO LUMINESCENT 2,2'-BIPYRIDYL COMPLEXES OF RHENIUM - PREPARATION AND SPECTRAL AND REDOX PROPERTIES OF MONO(BIPYRIDYL) COMPLEXES OF RHENIUM(III) AND RHENIUM(I) [J].
CASPAR, JV ;
SULLIVAN, BP ;
MEYER, TJ .
INORGANIC CHEMISTRY, 1984, 23 (14) :2104-2109
[10]   APPLICATION OF THE ENERGY-GAP LAW TO THE DECAY OF CHARGE-TRANSFER EXCITED-STATES [J].
CASPAR, JV ;
KOBER, EM ;
SULLIVAN, BP ;
MEYER, TJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (02) :630-632
12345678910