Synthesis, Crystal Structure and Luminescent Property of a New Double Helix Complex [Cd2L2(2,2′-bipy)2]n

被引：0

作者：

Chen Jing ^{[1
]}

Yin Jian-Ling ^{[1
]}

Wang Xiao-Juan ^{[1
]}

Feng Yun-Long ^{[1
]}

机构：

[1] Zhejiang Normal Univ, Zhejiang Key Lab React Chem Solid Surfaces, Inst Phys Chem, Jinhua 321004, Zhejiang, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 26卷 / 07期

关键词：

1,4-benzenebis(thioacetic acid); crystal structure; double helix structure; luminescent property; COORDINATION POLYMERS; ORGANIC FRAMEWORKS; CHAINS; PHOTOLUMINESCENCE; CHANNELS; NETWORK; ZN(II); ACID;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A flexible carboxylic ligand, 1,4-benzenebis(thioacetic acid) (H2L), has been employed to assemble with Cd(II) ions under hydrothermal conditions, generating a new complex [Cd2L2(2,2'-bipy)(2)](n) (1). X-ray diffraction reveals the complex 1 possesses a self-assembly double helix structure deriving from [Cd2L2(2,2'-bipy)(2)] units linked by L(2-)ligands. A 3D infinite framework is constructed via pi-pi stacking of 2,2' -bipy. The photoluminescent properties in solid state were investigated. CCDC: 705078.

引用

页码：1311 / 1314

页数：4

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