Synthesis and Structural Characterization of Lanthanide-Containing Polytungsto-antimonate [{Sb3(μ3-O)2Ln(H2O)Ln(H2O)2}2(SbW10O37)2(SbW8O31)2]22-Molecules Deriving from the Decomposition of the [Sb8W36O132]24-Macroanion

被引：1

作者：

Dufaye, Maxime ^{[1
]}

Duval, Sylvain ^{[1
]}

Stoclet, Gregory ^{[2
]}

Mara, Dimitrije ^{[3
]}

Van Deun, Rik ^{[3
]}

Loiseau, Thierry ^{[1
]}

机构：

[1] Univ Lille, Unite Catalyse & Chim Solide UCCS, UMR CNRS 8181, Cent Lille,Univ Artois, F-59000 Lille, France

[2] Univ Lille, UMR CNRS 8207, Unite Mat & Transformat UMET, Cent Lille, F-59000 Lille, France

[3] Univ Ghent, Dept Chem, Luminescent Lanthanide Lab L3, Krijgslaan 281,S3, B-9000 Ghent, Belgium

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2020年 / 2020卷 / 40期

关键词：

Polyoxometalates; Single-crystal X-ray diffraction; Lanthanides; Luminescence; SAXS; BUILDING-BLOCKS; POLYOXOMETALATE; CLUSTERS; HETEROPOLYTUNGSTATE; DIVERSITY; CHEMISTRY;

D O I：

10.1002/ejic.202000613

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of the tungsto-antimonate [Sb8W36O132](24-)polyoxometalate with late trivalent lanthanide cations (from Gd to Lu) gives rise to the formation of eight isostructural molecular compounds [{Sb-3(mu(3)-O)(2)Ln(H2O)Ln(H2O)(2)(SbW10O37)(SbW8O31)}(2)](22-)(Ln = Gd-III(1), Tb-III(2), Dy-III(3), Ho-III(4), Er-III(5), Tm-III(6), Yb-III(7), Lu-III(8)). All compounds were characterized by routine solid-state techniques (IR spectroscopy, TGA, single-crystal X-ray diffraction) and, by SAXS measurements in aqueous solutions to assess their stabilities. Luminescent properties of compounds5and7were also studied.

引用

页码：3837 / 3845

页数：9

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