Diatomite-supported manganese Schiff base: An efficient catalyst for oxidation of hydrocarbons

被引：74

作者：

Bahramian, Bahram ^{[1
]}

Ardejani, Faramarz Doulati ^{[2
]}

Mirkhani, Valiollah ^{[3
]}

Badii, Khashayar ^{[4
]}

机构：

[1] Shahrood Univ Technol, Coll Chem, Shahrood, Iran

[2] Shahrood Univ Technol, Fac Min & Geophys, Shahrood, Iran

[3] Isfahan Univ, Dept Chem, Esfahan 8174673441, Iran

[4] ICPC, Tehran, Iran

来源：

APPLIED CATALYSIS A-GENERAL | 2008年 / 345卷 / 01期

关键词：

diatomite; manganese(III)-salophen; periodate; epoxidation; hydroxylation;

D O I：

10.1016/j.apcata.2008.04.028

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The manganese(III)-salophen complex has been successfully immobilized for the first time on natural diatomite by a simple procedure. This catalyst was characterized by FT-IR, UV-vis, SEM and elemental analysis. The new catalytic material has been evaluated as oxidation catalyst. Our results show that these composite exhibit significant catalytic activities for alkene epoxidation and alkane hydroxylation using sodium periodate as oxidant. (C) 2008 Elsevier B.V. All rights reserved.

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收藏

页码：97 / 103

页数：7

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