Influence of CH2Cl2 for the structure stabilization of the NiII complex [Ni{6-MeO(O)CC6H4NHC(S)NP(S)(OiPr)2-1,5-S,S′}2]•CH2Cl2

被引：9

作者：

Babashkina, Maria G. ^{[1
]}

Safin, Damir A. ^{[1
]}

Srebro, Monika ^{[2
]}

Kubisiak, Piotr ^{[2
]}

Mitoraj, Mariusz P. ^{[2
]}

Bolte, Michael ^{[3
]}

Garcia, Yann ^{[1
]}

机构：

[1] Catholic Univ Louvain, Inst Condensed Matter & Nanosci, MOST Inorgan Chem, B-1348 Louvain, Belgium

[2] Jagiellonian Univ, Fac Chem, Dept Theoret Chem, PL-30060 Krakow, Poland

[3] Goethe Univ Frankfurt, Inst Anorgan Chem, Frankfurt, Germany

来源：

CRYSTENGCOMM | 2012年 / 14卷 / 02期

关键词：

MOLECULAR-STRUCTURES; COORDINATION; CHEMISTRY; THIOUREA; CRYSTAL; LIGANDS; NI(II);

D O I：

10.1039/c1ce06322g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of the deprotonated N-thiophosphorylated thiourea 6-MeO(O)CC6H4NHC(S)NHP(S)(OiPr)(2) (HL) with NiCl2 leads to violet [NiL2]center dot CH2Cl2 crystals, which were isolated by recrystallization from a mixture of CH2Cl2 and n-hexane. It was established that the deprotonated ligands, L, are 1,5-S,S'-coordinated. The influence of CH2Cl2 for the complex stabilization was studied.

引用

页码：370 / 373

页数：4

共 19 条

[1] Solvent-induced 1,3-N,S- vs. 1,5-S,S′-coordination in the NiII complex [Ni{p-Me2NC6H4NHC(S)NP(S)(OiPr)2}2] [J].

Babashkina, Maria G. ;

Safin, Damir A. ;

Srebro, Monika ;

Kubisiak, Piotr ;

Mitoraj, Mariusz P. ;

Bolte, Michael ;

Garcia, Yann .

CRYSTENGCOMM, 2011, 13 (17) :5321-5327

[2] Intramolecular hydrogen bonding controls 1,3-N,S- vs. 1,5-S,S′-coordination in NiII complexes of N-thiophosphorylated thioureas RNHC(S)NHP(S)(OiPr)2 [J].

Babashkina, Maria G. ;

Safin, Damir A. ;

Bolte, Michael ;

Srebro, Monika ;

Mitoraj, Mariusz ;

Uthe, Andre ;

Klein, Axel ;

Koeckerling, Martin .

DALTON TRANSACTIONS, 2011, 40 (13) :3142-3153

[3] Intramolecular hydrogen bond controlled coordination of N-thiophosphorylated thiourea 2,6-Me2C6H3NHC(S)NHP(S)(OiPr)2 with Ni(II) [J].

Babashkina, Maria G. ;

Safin, Damir A. ;

Bolte, Michael ;

Klein, Axel .

INORGANIC CHEMISTRY COMMUNICATIONS, 2009, 12 (07) :678-681

[4]

Baerends E. J., THEORETICAL CHEM

[5] Hydrogen-bonding networks in a bipodal acyl-thiourea and its NiII 2:2 metallamacrocyclic complex [J].

Bourne, SA ;

Hallale, O ;

Koch, KR .

CRYSTAL GROWTH & DESIGN, 2005, 5 (01) :307-312

[6]

Frisch M. J., 2016, Gaussian 03 Revision B.03

[7] Electronic structure and spectral, of ruthenium diimine complexes by density functional theory and INDO/S. Comparison of the two methods [J].

Gorelsky, SI ;

Lever, ABP .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 635 (1-2) :187-196

[8]

Gorelsky SI., 2010, SWIZARD PROGRAM

[9] Thiophosphorus and related ligands in coordination, organometallic and supramolecular chemistry. A personal account [J].

Haiduc, I .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 623 (1-2) :29-42

[10]

Haiduc I., 2010, INORGANIC EXPT, P229

← 1 2 →