Crystal structure of the coordination polymer [Cu2(S-mal)2(bpy)2(H2O)]•2.5H2O

被引:4
|
作者
Zavakhina, M. S. [1 ,2 ]
Samsonenko, D. G. [1 ,2 ]
Fedin, V. P. [1 ,2 ]
机构
[1] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk, Russia
[2] Novosibirsk Natl Res State Univ, Novosibirsk, Russia
关键词
copper; coordination polymers; metal-organic frameworks; chiral complexes; malic acid; METAL-ORGANIC FRAMEWORKS; TOPOLOGIES;
D O I
10.1134/S0022476615010151
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
In the interaction of basic copper carbonate with optically pure malic acid and 4,4'-bipyridine [Cu-2(S-mal)(2)(bpy)(2)(H2O)]center dot 2.5H(2)O (1) is obtained. The structure of the metal-organic coordination polymer is unique for this class of compounds, which is established by the single crystal X-ray diffraction analysis using synchrotron radiation.
引用
收藏
页码:108 / 112
页数:5
相关论文
共 50 条
  • [41] Rational design of homo and hetero hexanuclear coordination compounds:: Syntheses and magnetic properties of [Cu2IIM4II] (M = Cu, Ni) species and the crystal structure of {[Cu(tmen)(H2O)]2[Cu(tmen)]2[Cu2L] (H2O)}(ClO4)4•2 H2O
    Aukauloo, A
    Ottenwaelder, X
    Ruiz, R
    Journaux, Y
    Pei, Y
    Rivière, E
    Muñoz, MC
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2000, (05) : 951 - 957
  • [42] Synthesis, Crystal Structure and Magnetic Property of a Coordination Polymer [Fe(HL)(H2O)]n
    Zhao Su-Qin
    Gu Jin-Zhong
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2016, 32 (05) : 853 - 858
  • [43] Supramolecular Coordination Assemblies Using 2-Aminodiacetic Terephthalic Acid Ligands: K[NiII(Hadta)(H2O)2]·H2O and K[Cu1.5II(adta)(H2O)1.5]·H2O
    David P. Walsh
    Lei Zhang
    Paul E. Kruger
    Wolfgang Schmitt
    Journal of Inorganic and Organometallic Polymers and Materials, 2011, 21
  • [44] Synthesis, characterization and crystal structure of a new layered heterometallic coordination polymer {[(CuL) 2Sr(H2O)•Sr2(H2O)7]•2H2O•0.5CH3OH}n
    Tao Ruo-Jie
    Liu Bao-Lin
    Li Fu-An
    Cheng Yan-Xiang
    Niu Jing-Yang
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2006, 27 (08): : 1400 - 1403
  • [45] Heat capacities and thermodynamic properties of [Co(AIP)(BPY)0.5•H2O]n•2nH2O
    Li, Jiajie
    Xu, Fen
    Si, Xiaoliang
    Sun, Lixian
    Jiao, Qingzhu
    Jiao, Chengli
    Gu, Zhizhi
    Xin, He
    THERMOCHIMICA ACTA, 2013, 566 : 15 - 18
  • [46] Syntheses and Structures of Two Novel Interdigitated Metal-Quinolone Complexes: [Cu2(cfH)2(bptc)(H2O)]•4H2O and [Zn2(levofH)2(odpa)]•5.5H2O
    Zhang, Jin-Ling
    Yang, Juan
    Wang, Xin
    Zhang, Hua-Yi
    Chi, Xiao-Lin
    Chen, Yu
    Yang, Qi
    Xiao, Dong-Rong
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2015, 641 (05): : 820 - 825
  • [47] Synthesis and Crystal Structure of a Novel Heterometallic Complex [Na2Cu2Gd2(pdc)4(H2O)14·2H2O]
    王燕
    郭翠莲
    郑和根
    沈应中
    Chinese Journal of Structural Chemistry, 2009, 28 (01) : 94 - 98
  • [48] Synthesis, property and crystal structure of the new sandwich type heteropolytungstate (Hpy)4Na2H2[Cu(H2O){WO(H2O)}(WO)(AsW9O33)2]•5H2O
    Xue, GL
    Liu, B
    Li, HX
    Wang, JW
    Wang, DQ
    ACTA CHIMICA SINICA, 2003, 61 (04) : 567 - 572
  • [49] Three pimelato-bridged Cu(II) phenanthroline complexes:: [Cu2(phen)2(H2O)2L2]•4H2O, α- and β-[Cu2(phen)2L2]•4H2O, H2L = HOOC(CH2)5COOH
    Ge, CX
    Zheng, YQ
    JOURNAL OF COORDINATION CHEMISTRY, 2005, 58 (14) : 1199 - 1208
  • [50] Synthesis and Crystal Structure of a Novel Heterometallic Complex [Na2Cu2Gd2(pdc)4(H2O)14•2H2O]
    Wang Yan
    Guo Cui-Lian
    Zheng He-Gen
    Shen Ying-Zhong
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2009, 28 (01) : 94 - 98